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PVP-AŞILANMIŞ NiFe2O4 NANO PARÇACIKLARININ YÜZEY POLİMERİZASYONU TEKNİĞİ İLE SENTEZİ

Yıl 2018, Cilt: 6 Sayı: 2, 188 - 197, 01.06.2018

Sema Vural Aysel Alphan Süleyman Köytepe Turgay Seçkın

https://doi.org/10.15317/Scitech.2018.125

Öz

Nikel ferrit nano parçacıkları, surfaktant destekli hidrotermal teknik kullanılarak, kontrollü parçacık boyutu ve boyut dağılımı ile sentezlenmiştir. Manyetik nano parçacıkların yüzey modifikasyonu (3-chloropropyl)triethoxysilane ile gerçekleştirilmiştir. Modifiye edilen nano parçacıklar yüzeyden başlatılan polimerizasyon tekniği kullanılarak PVP ile aşı polimer yapısında kaplanmıştır. Elde edilen spinel ferritlerin kristal yapısı ve boyutu X-Işını Kırınım Analizi (XRD) ve Taramalı Elektron Mikroskopu (SEM) ile araştırılmıştır. Nano parçacıkların ve nano kompozitlerin manyetik özellikleri Titreşimli Örnek Magnetometresi (VSM) kullanılarak incelenmiştir. Elde edilen NiFe2O4 nano parçacıklarının ortalama parçacık boyutu 24 nm’dir. Oda sıcaklığında süper paramagnetik karakter ve yüksek doygunluk manyetizasyonu göstermektedir. Gerçekleştirilen sentez stratejisinin biyo-uygulamalarda kullanılacak gelişmiş malzemelerin sentezinde etkili bir yöntem olabileceği düşünülmektedir.

Anahtar Kelimeler

Manyetik malzeme NiFe2O4 Spinel ferrit Yüzey modifikasyonu

Kaynakça

  • Akbarzadeh, A., Samiei, M., Davaran, S., 2012, “Magnetic Nanoparticles: Preparation, Physical Properties, and Applications in Biomedicine”, Nanoscale Research Letters, Vol. 7 (1), pp. 144-157.
  • Alarifi, A., Deraz, N. M., Shaban, S., 2009, “Structural, Morphological and Magnetic Properties of NiFe2O4 Nano-Particles”, Journal of Alloys and Compounds, Vol. 486(1-2), pp. 501-506.
  • Dilnawaz, F., Singh, A., Mohanty, C., Sahoo, S.K., 2010, “Dual Drug Loaded Superparamagnetic Iron Oxide Nanoparticles for Targeted Cancer Therapy”, Biomaterials, Vol. 31(13), pp. 3694–3706.
  • El-Sayed, A. M., 2002, “Influence of Zinc Content on Some Properties of Ni-Zn ferrites”, Ceramics International, Vol. 28 (4), pp. 363-367.
  • Franco, V., Gutfleisch, O., 2012, “Magnetic Materials for Energy Applications”, JOM Journal of the Minerals, Metals and Materials Society, Vol. 64 (7), pp. 750-751.
  • Fu, Y-P., Pan, K-Y., Lin, C-H., 2002, “Microwave-induced Combustion Synthesis of Ni0.25Cu0.25Zn0.5 Ferrite Powders and Their Characterizations”, Materials Letters, Vol. 57 (2), pp. 291-296.
  • Garcell, L., Morales, M. P., Andres-Verges, M., Tartaj, P., Serna, C. J., 1998, “Interfacial and Rheological Characteristics of Maghemite Aqueous Suspensions”, Journal of Colloid and Interface Science, Vol. 205 (2), pp. 470-475.
  • Giri, N., Natarajan, R. K., Gunasekaran, S., Shreemathi, S., 2011, “13C NMR and FTIR Spectroscopic Study of Blend Behavior of PVP and Nano Silver Particles”, Archives of Applied Science Research, Vol. 3, pp. 624-630.
  • Haun, J. B., Yoon, T. J., Lee, H., Weissleder, R., 2010, “Magnetic Nanoparticle Biosensors”, Wiley Interdiscip. Rev.: Nanomed. Nanobiotechnol, Vol. 2, pp. 291–304.
  • Hu, L., Mao, Z., Gao, C., 2009, “Colloidal Particles for Cellular Uptake and Delivery”, Journal of Materials Chemistry, Vol. 19 (20), pp. 3108-3115.
  • Issa, B., Obaidat, I.M., Albiss, B. A., Haik, Y., 2013, “Magnetic Nanoparticles: Surface Effects and Properties Related to Biomedicine Applications”, International Journal of Molecular Sciences, Vol. 14, pp. 21266-21305.
  • Latorre, M., Rinaldi, C., 2009, “Applications of Magnetic Nanoparticles in Medicine: Magnetic Fluid Hyperthermia”, Puerto Rico Health Sciences Journal , Vol. 28, pp. 227-238.
  • Laurent, S., Dutz, S., Hafeli, U. O., Mahmoudi, M., 2011, “Magnetic Fluid Hyperthermia: Focus on Superparamagnetic Iron Oxide Nanoparticles”, Advances in Colloid and Interface Science, Vol. 166, pp. 8–23.
  • Li, G-Y., Jiang, Y-R., Huang, K-L., Ding, P., Chen, J., 2008, “Preparation and Properties of Magnetic Fe3O4-Chitosan Nanoparticles”, Journal of Alloys and Compounds, Vol. 466, pp. 451-456.
  • Li, Z., Yi, P. W., Sun, Q., Lei, H., Zhao, H. L., Zhu, Z. H., Smith, S. C., Lan, M. B., Lu, G. Q. M., 2012, “Ultrasmall Water-Soluble and Biocompatible Magnetic Iron Oxide Nanoparticles as Positive and Negative Dual Contrast Agents”, Advanced Functional Materials, Vol. 22 (11), pp. 2387–2393.
  • Manova, E., Tsoncheva, T., Estournes, C., Paneva, D., Tenchev, K., Mitov, I., Petrov, L., 2006, “Nanosized Iron and Iron-Cobalt Spinel Oxides as Catalysts for Methanol Decomposition”, Applied Catalysis A: General, Vol. 300 (2), pp. 170-180.
  • Na, H. B., Song, I. C., Hyeon, T., 2009, “Inorganic Nanoparticles for MRI Contrast Agents”, Advanced Materials, Vol. 21 (21), pp. 2133–2148.
  • Nathani, H., Gubbala, S., Misra, R. D. K., 2005, “Magnetic Behavior of Nanocrystalline Nickel Ferrite: Part I. The effect of Surface Roughness”, Materials Science and Engineering: B, Vol. 121, pp. 126-136.
  • Nejati, K., Zabihi, R., 2012, “Preparation and Magnetic Properties of Nano Size Nickel Ferrite Particles using Hydrothermal Method”, Chemistry Central Journal, Vol. 6, pp. 1-6.
  • Niasari, S. M., Davar, F., Mahmoudi, T., 2009, “A Simple Route to Synthesize Nanocrystalline Nickel Ferrite (NiFe2O4) in The Presence of Octanoic Acid as a Surfactant”, Polyhedron, Vol. 28 (8), pp. 1455-1458.
  • Philipse, A.P ., Bruggen, M. P., Pathmamanoharan, C., 1994, “Magnetic Silica Dispersions: Preparation and Stability of Surface-Modified Silica Particles with a Magnetic Core”, Langmuir, Vol. 10(1), pp. 92-99.
  • Rashad, M. M., Elsayed, E. M., Moharam, M. M., Abou-Shahba, R. M., Saba, A. E., 2009, “Structure and Magnetic Properties of NixZn1-xFe2O4 Nanoparticles Prepared Through Co-precipitation Method”, Journal of Alloys and Compounds, Vol. 486, pp. 759-767.
  • Sun, B., Huang, L., Na, N., He, D., Ouyang, J., 2011, “Applications of multifunctional magnetic nanoparticles for the enrichment of proteins for PAGE separation”, Electrophoresis, Vol. 32, pp. 2091–2098.
  • Tartaj, P., Morales, M. P., Verdaguer, S., Carreno, T., Serna, C.J., 2003, “The Preparation of Magnetic Nanoparticles for Applications in Biomedicine”, Journal of Physics D: Applied Physics, Vol. 36 (13), pp. R182–R197.
  • Xie, J., Huang, J., Li, X., Sun, S., Chen, X., 2009, “Iron Oxide Nanoparticle Platform for Biomedical Applications”, Current Medicinal Chemistry, Vol. 16 (10), pp. 1278–1294.
  • Zhi, J., Wang, Y., Lu, Y., Ma, J., Luo, G., 2006, “In Situ Preparation of Magnetic Chitosan/Fe3O4 Composite Nanoparticles in Tiny Pools of Water-in-oil Microemulsion”, Reactive and Functional Polymers, Vol. 66, pp. 1552-1558.
  • Zhou, L., He, B., Zhang, F., 2012, “Facile One-Pot Synthesis of Iron Oxide Nanoparticles Cross-linked Magnetic Poly (vinyl alcohol) Gel Beads for Drug Delivery”, ACS Applied Materials & Interfaces, Vol. 4 (1), pp. 192–199.
  • Zhu, W., Li, Y., Zeng, F., Yin, H., Wang, L., Zhu, H., 2015, “Superparamagnetic Fe3O4 Nanoparticles Modified by Water-Soluble and Biocompatible Polyethylenimine for Lipase Immobilization with Physical and Chemical Mechanisms”, RSC Advances, Vol. 5 (29), pp. 23039–23045.

Synthesis of PVP-grafted NiFe2O4 Nanoparticles with the Surface Initiated Polymerization Technique

Yıl 2018, Cilt: 6 Sayı: 2, 188 - 197, 01.06.2018

Sema Vural Aysel Alphan Süleyman Köytepe Turgay Seçkın

https://doi.org/10.15317/Scitech.2018.125

Öz

Nickel ferrite nanoparticles have been synthesized using the surfactant assistant hydrothermally technique with well controlled particle size and size distribution. The surface modification of magnetic nanoparticles was achieved using (3-chloropropyl)triethoxysilane. Modified nanoparticles were grafted with PVP using surface initialized radical polymerization. Crystal structure and crystallite size of the produced spinel ferrites were investigated by X-ray diffraction analysis (XRD) and scanning electron microscope (SEM). The magnetic properties of nanoparticles and nanocomposite were examined using a vibrating sample magnetometer (VSM). The NiFe2O4 nanoparticles with average size of 24 nm, were exhibited superparamagnetism and high saturation magnetization at room temperature. The synthesized strategy is thought to be an effective method in the synthesis of advanced materials to be used in bio-applications.

Anahtar Kelimeler

Magnetic materials NiFe2O4 Spinel ferrite Surface modification

Kaynakça

  • Akbarzadeh, A., Samiei, M., Davaran, S., 2012, “Magnetic Nanoparticles: Preparation, Physical Properties, and Applications in Biomedicine”, Nanoscale Research Letters, Vol. 7 (1), pp. 144-157.
  • Alarifi, A., Deraz, N. M., Shaban, S., 2009, “Structural, Morphological and Magnetic Properties of NiFe2O4 Nano-Particles”, Journal of Alloys and Compounds, Vol. 486(1-2), pp. 501-506.
  • Dilnawaz, F., Singh, A., Mohanty, C., Sahoo, S.K., 2010, “Dual Drug Loaded Superparamagnetic Iron Oxide Nanoparticles for Targeted Cancer Therapy”, Biomaterials, Vol. 31(13), pp. 3694–3706.
  • El-Sayed, A. M., 2002, “Influence of Zinc Content on Some Properties of Ni-Zn ferrites”, Ceramics International, Vol. 28 (4), pp. 363-367.
  • Franco, V., Gutfleisch, O., 2012, “Magnetic Materials for Energy Applications”, JOM Journal of the Minerals, Metals and Materials Society, Vol. 64 (7), pp. 750-751.
  • Fu, Y-P., Pan, K-Y., Lin, C-H., 2002, “Microwave-induced Combustion Synthesis of Ni0.25Cu0.25Zn0.5 Ferrite Powders and Their Characterizations”, Materials Letters, Vol. 57 (2), pp. 291-296.
  • Garcell, L., Morales, M. P., Andres-Verges, M., Tartaj, P., Serna, C. J., 1998, “Interfacial and Rheological Characteristics of Maghemite Aqueous Suspensions”, Journal of Colloid and Interface Science, Vol. 205 (2), pp. 470-475.
  • Giri, N., Natarajan, R. K., Gunasekaran, S., Shreemathi, S., 2011, “13C NMR and FTIR Spectroscopic Study of Blend Behavior of PVP and Nano Silver Particles”, Archives of Applied Science Research, Vol. 3, pp. 624-630.
  • Haun, J. B., Yoon, T. J., Lee, H., Weissleder, R., 2010, “Magnetic Nanoparticle Biosensors”, Wiley Interdiscip. Rev.: Nanomed. Nanobiotechnol, Vol. 2, pp. 291–304.
  • Hu, L., Mao, Z., Gao, C., 2009, “Colloidal Particles for Cellular Uptake and Delivery”, Journal of Materials Chemistry, Vol. 19 (20), pp. 3108-3115.
  • Issa, B., Obaidat, I.M., Albiss, B. A., Haik, Y., 2013, “Magnetic Nanoparticles: Surface Effects and Properties Related to Biomedicine Applications”, International Journal of Molecular Sciences, Vol. 14, pp. 21266-21305.
  • Latorre, M., Rinaldi, C., 2009, “Applications of Magnetic Nanoparticles in Medicine: Magnetic Fluid Hyperthermia”, Puerto Rico Health Sciences Journal , Vol. 28, pp. 227-238.
  • Laurent, S., Dutz, S., Hafeli, U. O., Mahmoudi, M., 2011, “Magnetic Fluid Hyperthermia: Focus on Superparamagnetic Iron Oxide Nanoparticles”, Advances in Colloid and Interface Science, Vol. 166, pp. 8–23.
  • Li, G-Y., Jiang, Y-R., Huang, K-L., Ding, P., Chen, J., 2008, “Preparation and Properties of Magnetic Fe3O4-Chitosan Nanoparticles”, Journal of Alloys and Compounds, Vol. 466, pp. 451-456.
  • Li, Z., Yi, P. W., Sun, Q., Lei, H., Zhao, H. L., Zhu, Z. H., Smith, S. C., Lan, M. B., Lu, G. Q. M., 2012, “Ultrasmall Water-Soluble and Biocompatible Magnetic Iron Oxide Nanoparticles as Positive and Negative Dual Contrast Agents”, Advanced Functional Materials, Vol. 22 (11), pp. 2387–2393.
  • Manova, E., Tsoncheva, T., Estournes, C., Paneva, D., Tenchev, K., Mitov, I., Petrov, L., 2006, “Nanosized Iron and Iron-Cobalt Spinel Oxides as Catalysts for Methanol Decomposition”, Applied Catalysis A: General, Vol. 300 (2), pp. 170-180.
  • Na, H. B., Song, I. C., Hyeon, T., 2009, “Inorganic Nanoparticles for MRI Contrast Agents”, Advanced Materials, Vol. 21 (21), pp. 2133–2148.
  • Nathani, H., Gubbala, S., Misra, R. D. K., 2005, “Magnetic Behavior of Nanocrystalline Nickel Ferrite: Part I. The effect of Surface Roughness”, Materials Science and Engineering: B, Vol. 121, pp. 126-136.
  • Nejati, K., Zabihi, R., 2012, “Preparation and Magnetic Properties of Nano Size Nickel Ferrite Particles using Hydrothermal Method”, Chemistry Central Journal, Vol. 6, pp. 1-6.
  • Niasari, S. M., Davar, F., Mahmoudi, T., 2009, “A Simple Route to Synthesize Nanocrystalline Nickel Ferrite (NiFe2O4) in The Presence of Octanoic Acid as a Surfactant”, Polyhedron, Vol. 28 (8), pp. 1455-1458.
  • Philipse, A.P ., Bruggen, M. P., Pathmamanoharan, C., 1994, “Magnetic Silica Dispersions: Preparation and Stability of Surface-Modified Silica Particles with a Magnetic Core”, Langmuir, Vol. 10(1), pp. 92-99.
  • Rashad, M. M., Elsayed, E. M., Moharam, M. M., Abou-Shahba, R. M., Saba, A. E., 2009, “Structure and Magnetic Properties of NixZn1-xFe2O4 Nanoparticles Prepared Through Co-precipitation Method”, Journal of Alloys and Compounds, Vol. 486, pp. 759-767.
  • Sun, B., Huang, L., Na, N., He, D., Ouyang, J., 2011, “Applications of multifunctional magnetic nanoparticles for the enrichment of proteins for PAGE separation”, Electrophoresis, Vol. 32, pp. 2091–2098.
  • Tartaj, P., Morales, M. P., Verdaguer, S., Carreno, T., Serna, C.J., 2003, “The Preparation of Magnetic Nanoparticles for Applications in Biomedicine”, Journal of Physics D: Applied Physics, Vol. 36 (13), pp. R182–R197.
  • Xie, J., Huang, J., Li, X., Sun, S., Chen, X., 2009, “Iron Oxide Nanoparticle Platform for Biomedical Applications”, Current Medicinal Chemistry, Vol. 16 (10), pp. 1278–1294.
  • Zhi, J., Wang, Y., Lu, Y., Ma, J., Luo, G., 2006, “In Situ Preparation of Magnetic Chitosan/Fe3O4 Composite Nanoparticles in Tiny Pools of Water-in-oil Microemulsion”, Reactive and Functional Polymers, Vol. 66, pp. 1552-1558.
  • Zhou, L., He, B., Zhang, F., 2012, “Facile One-Pot Synthesis of Iron Oxide Nanoparticles Cross-linked Magnetic Poly (vinyl alcohol) Gel Beads for Drug Delivery”, ACS Applied Materials & Interfaces, Vol. 4 (1), pp. 192–199.
  • Zhu, W., Li, Y., Zeng, F., Yin, H., Wang, L., Zhu, H., 2015, “Superparamagnetic Fe3O4 Nanoparticles Modified by Water-Soluble and Biocompatible Polyethylenimine for Lipase Immobilization with Physical and Chemical Mechanisms”, RSC Advances, Vol. 5 (29), pp. 23039–23045.
Toplam 28 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Makaleler
Yazarlar

Sema Vural

Aysel Alphan Bu kişi benim

Süleyman Köytepe

Turgay Seçkın Bu kişi benim

Yayımlanma Tarihi 1 Haziran 2018
Yayımlandığı Sayı Yıl 2018 Cilt: 6 Sayı: 2

Kaynak Göster

APA Vural, S., Alphan, A., Köytepe, S., Seçkın, T. (2018). PVP-AŞILANMIŞ NiFe2O4 NANO PARÇACIKLARININ YÜZEY POLİMERİZASYONU TEKNİĞİ İLE SENTEZİ. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, 6(2), 188-197. https://doi.org/10.15317/Scitech.2018.125
AMA Vural S, Alphan A, Köytepe S, Seçkın T. PVP-AŞILANMIŞ NiFe2O4 NANO PARÇACIKLARININ YÜZEY POLİMERİZASYONU TEKNİĞİ İLE SENTEZİ. sujest. Haziran 2018;6(2):188-197. doi:10.15317/Scitech.2018.125
Chicago Vural, Sema, Aysel Alphan, Süleyman Köytepe, ve Turgay Seçkın. “PVP-AŞILANMIŞ NiFe2O4 NANO PARÇACIKLARININ YÜZEY POLİMERİZASYONU TEKNİĞİ İLE SENTEZİ”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 6, sy. 2 (Haziran 2018): 188-97. https://doi.org/10.15317/Scitech.2018.125.
EndNote Vural S, Alphan A, Köytepe S, Seçkın T (01 Haziran 2018) PVP-AŞILANMIŞ NiFe2O4 NANO PARÇACIKLARININ YÜZEY POLİMERİZASYONU TEKNİĞİ İLE SENTEZİ. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 6 2 188–197.
IEEE S. Vural, A. Alphan, S. Köytepe, ve T. Seçkın, “PVP-AŞILANMIŞ NiFe2O4 NANO PARÇACIKLARININ YÜZEY POLİMERİZASYONU TEKNİĞİ İLE SENTEZİ”, sujest, c. 6, sy. 2, ss. 188–197, 2018, doi: 10.15317/Scitech.2018.125.
ISNAD Vural, Sema vd. “PVP-AŞILANMIŞ NiFe2O4 NANO PARÇACIKLARININ YÜZEY POLİMERİZASYONU TEKNİĞİ İLE SENTEZİ”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi 6/2 (Haziran 2018), 188-197. https://doi.org/10.15317/Scitech.2018.125.
JAMA Vural S, Alphan A, Köytepe S, Seçkın T. PVP-AŞILANMIŞ NiFe2O4 NANO PARÇACIKLARININ YÜZEY POLİMERİZASYONU TEKNİĞİ İLE SENTEZİ. sujest. 2018;6:188–197.
MLA Vural, Sema vd. “PVP-AŞILANMIŞ NiFe2O4 NANO PARÇACIKLARININ YÜZEY POLİMERİZASYONU TEKNİĞİ İLE SENTEZİ”. Selçuk Üniversitesi Mühendislik, Bilim Ve Teknoloji Dergisi, c. 6, sy. 2, 2018, ss. 188-97, doi:10.15317/Scitech.2018.125.
Vancouver Vural S, Alphan A, Köytepe S, Seçkın T. PVP-AŞILANMIŞ NiFe2O4 NANO PARÇACIKLARININ YÜZEY POLİMERİZASYONU TEKNİĞİ İLE SENTEZİ. sujest. 2018;6(2):188-97.

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