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An Investigation of the Chemical Composition of Bottom Sediments from Dried Lake Gavur of Turkiye by Using XRF and Multivariate Data Analysis

Yıl 2024, Cilt: 37 Sayı: 2, 793 - 811

Muhammet Topuz Muharrem Keskin Murat Karabulut Nurgül Karlıoğlu Kılıç

https://doi.org/10.35378/gujs.1240178

Öz

Lake sediments offer valuable information about the geographical, climatic and environmental variations. This work was carried out to examine the chemical elements of eleven sediment samples from the old bottom (0-5m; 0.5m increments) of the dried Lake Gavur in Turkiye by applying XRF along with PCA and PLSR data analyses methods. The highest and negative correlations were observed for Sr (-0.89), S+SO3 (-0.74) and Zr+ZrO2 (-0.61) with sampling depths meaning that their concentrations were lower in deeper locations (4.0-5.0 m). In contrast, Ti+TiO2 (0.60), Al+Al2O3 (0.53) and Cu+CuO (0.51) had high and positive correlations and their quantities increased as the depth increased. The age of the two samples (at 2.5 m and 5.0 m) was determined as 4752±33 BP years (2.5 m) and 5470±35 BP (5.0 m). Ca+CaO content was found as lower and Ti+TiO was higher in the deeper sediment (5.0 m) indicating rainy periods. PCA clustered the samples into two groups as deeper samples (4.0-5.0 m) and other samples (0.0 3.5m) while PLSR grouped them into three clusters as deeper (4.0-5.0 m), medium-depth (1.5 3.5 m) and shallower (0.0-1.0m) samples. PLSR model had a good performance to estimate the sampling depth from the chemical elements (R2cal=0.95; R2val=0.67) which means that the variations of the chemicals were highly dependent on the sampling depth. A general comment that can be obtained for the lake from the geochemical proxies is that: After a rainy period between 5.0m and 4.0m, there was a gradual drought up to 2.5m and a maximum dry period at 2.5m. It was a wet period between 2.5m and 1.0m and the second period with maximum precipitation was not as effective as seen in the first one.

Anahtar Kelimeler

Lake Gavur Geochemical indicator XRF PCA PLSR

Destekleyen Kurum

Scientific Research Projects Unit of the Kahramanmaras Sutcu Imam University

Proje Numarası

(Project No: 2017/2-46D).

Teşekkür

This research was financially supported by the Scientific Research Projects Unit of the Kahramanmaras Sutcu Imam University (Project No: 2017/2-46D).

Kaynakça

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Yıl 2024, Cilt: 37 Sayı: 2, 793 - 811

Muhammet Topuz Muharrem Keskin Murat Karabulut Nurgül Karlıoğlu Kılıç

https://doi.org/10.35378/gujs.1240178

Öz

Anahtar Kelimeler

Dried Gavur Lake sediment geochemical indicator XRF PCA PLSR

Proje Numarası

(Project No: 2017/2-46D).

Kaynakça

  • [1] Cohen, A.S., “Paleolimnology: the history and evolution of lake systems”, Oxford University Press, New York, 528p, (2003).
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  • [3] Kukrer, S., “Comprehensive Risk Assessment of Heavy Metal Accumulation in Surface Sediment of Lake Tortum Based on Ecological Indices”, Turkish Journal of Agriculture –Food Science and Technology, 4(12): 1185-1191, (2016). (in Turkish with English abstract).
  • [4] Alexandrin, M.Y., Darin, A.V., Kalugin, I.A., Dolgova, E.A., Grachev, A.M., Solomina, O., “Annual Sedimentary Record from Lake Donguz-Orun (Central Caucasus) Constrained by High Resolution SR-XRF Analysis and Its Potential for Climate Reconstructions”, Frontiers in Earth Science, 6: 158, (2018).
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  • [7] Akcer On, S., Cagatay, N., Sakinc, M., “Sedimentary records of Little Ice Age and Medieval Warm Period in Kucukcekmece Lagoon”, ITU Journal, 10(4): 131-140, (2011). (in Turkish with English abstract).
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  • [10] Nazarova, L.B., Subetto, D.A., Syrykh, L.S., Grekov, I.M., Leontev, P.A., “Reconstructions of Paleoecological and Paleoclimatic Conditions of the Late Pleistocene and Holocene according to the Results of Chironomid Analysis of Sediments from Medvedevskoe Lake (Karelian Isthmus)”, Doklady Earth Sciences, 480(2): 710–714, (2018).
  • [11] Mutlu, G., Dogan, U., Atıcı, T., and Senkul, C., “Paleoenvironmental and paleoclimatic changes of Engir Lake (Central Anatolia) and its surroundings during the last 1090 years: The fossil diatom record”, Quaternary International. https://doi.org/10.1016/j.quaint.2022.09.011, (2022)
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  • [13] Gearey, B. R., Fletcher, A., Fletcher, W. G., Campbell, S., Boomer, I., Keen, D., Reed, J., and Tetlow, E., “From site to landscape: assessing the value of geoarchaeological data in understanding the archaeological record of Domuztepe, Eastern Mediterranean, Turkiye”, American Journal of Archaeology, 115(3): 465-482, (2011).
  • [14] Eker, F., “The Overview on Historical Geography of Kahramanmaras”, KSU Journal of Social Sciences, 10(2): 25-38, (2013).
  • [15] Atakuman, C., “Typological Features and Social Function of Halaf Period Seals from Domuztepe”, Hacettepe University Faculty of Letters Journal, 32(1): 59-92, (2015).
  • [16] Tekin, H., “The State of the Late Neolithic Pottery of Domuztepe in the Turkish Eastern Mediterranean”, American Journal of Physical Anthropology, 168: 676-686, (2019).
  • [17] Gebregiorgis, D., Giosan, L., Hathorne, E. C., Anand, P., Nilsson-Kerr, K., Plass, A., Luckge A., Clemens S.C., Frank, M., “What can we learn from X-ray fluorescence core scanning data? A paleomonsoon case study”, Geochemistry, Geophysics, Geosystems, 21, e2019GC008414, (2020).
  • [18] Vural, A., “Investigation of the relationship between rare earth elements, trace elements and major oxides in soil geochemistry”, Environmental Monitoring and Assessment, 192(2): 1-11, (2020).
  • [19] Oyedotun, T.D.T., “X-ray fluorescence (XRF) in the investigation of the composition of earth materials: a review and an overview”, Geology, Ecology, and Landscapes, 2(2): 148–154, (2018). doi.org/10.1080/24749508.2018.1452459
  • [20] Amosova, A. A., Chubarov, V. M., Pashkova, G. V., Finkelshtein, A. L., and Bezrukova, E. V. “Wavelength dispersive X-ray fluorescence determination of major oxides in bottom and peat sediments for paleoclimatic studies”, Applied Radiation and Isotopes, 144: 118-123, (2019).
  • [21] Topuz, M., Karabulut, M., “An Examination of Paleoclimatic Changes in Gâvur Lake (Kahramanmaras) During the Last 6000 Years Using Geochemical Indicators”, 1st Istanbul International Geography Congress Proceedings Book, 737-745, (2019). (in Turkish with English abstract).
  • [22] Dugerdil, L., Ménot, G., Peyron, O., Jouffroy-Bapicot, I., Ansanay-Alex, S., Antheaume, I., Behling, H., Boldgiv, B., Develle, A.L., Grossi, V., Magail, J., Makou, M., Robles, M., Unkelbach, J., Vanniere, B., and Joannin, S., “Late Holocene Mongolian climate and environment reconstructions from brGDGTs, NPPs and pollen transfer functions for Lake Ayrag: Paleoclimate implications for Arid Central Asia”, Quaternary Science Reviews, 273: 107235, (2021).
  • [23] Daryin, A. V., Kalugin, I. A., Maksimova, N. V., Smolyaninova, L. G., and Zolotarev, K.V., “Use of a scanning XRF analysis on SR beams from VEPP-3 storage ring for research of core bottom sediments from Teletskoe Lake with the purpose of high resolution quantitative reconstruction of last millennium paleoclimate”, Nuclear Instruments and Methods in Physics Research Section A. 43(1), 255-258, (2005).
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Toplam 66 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Mühendislik
Bölüm Environmental Science
Yazarlar

Muhammet Topuz 0000-0001-5526-3797

Muharrem Keskin 0000-0002-2649-6855

Murat Karabulut 0000-0002-1456-6908

Nurgül Karlıoğlu Kılıç 0000-0002-6255-6819

Proje Numarası (Project No: 2017/2-46D).
Erken Görünüm Tarihi 9 Aralık 2023
Yayımlanma Tarihi
Yayımlandığı Sayı Yıl 2024 Cilt: 37 Sayı: 2

Kaynak Göster

APA Topuz, M., Keskin, M., Karabulut, M., Karlıoğlu Kılıç, N. (t.y.). An Investigation of the Chemical Composition of Bottom Sediments from Dried Lake Gavur of Turkiye by Using XRF and Multivariate Data Analysis. Gazi University Journal of Science, 37(2), 793-811. https://doi.org/10.35378/gujs.1240178
AMA Topuz M, Keskin M, Karabulut M, Karlıoğlu Kılıç N. An Investigation of the Chemical Composition of Bottom Sediments from Dried Lake Gavur of Turkiye by Using XRF and Multivariate Data Analysis. Gazi University Journal of Science. 37(2):793-811. doi:10.35378/gujs.1240178
Chicago Topuz, Muhammet, Muharrem Keskin, Murat Karabulut, ve Nurgül Karlıoğlu Kılıç. “An Investigation of the Chemical Composition of Bottom Sediments from Dried Lake Gavur of Turkiye by Using XRF and Multivariate Data Analysis”. Gazi University Journal of Science 37, sy. 2 t.y.: 793-811. https://doi.org/10.35378/gujs.1240178.
EndNote Topuz M, Keskin M, Karabulut M, Karlıoğlu Kılıç N An Investigation of the Chemical Composition of Bottom Sediments from Dried Lake Gavur of Turkiye by Using XRF and Multivariate Data Analysis. Gazi University Journal of Science 37 2 793–811.
IEEE M. Topuz, M. Keskin, M. Karabulut, ve N. Karlıoğlu Kılıç, “An Investigation of the Chemical Composition of Bottom Sediments from Dried Lake Gavur of Turkiye by Using XRF and Multivariate Data Analysis”, Gazi University Journal of Science, c. 37, sy. 2, ss. 793–811, doi: 10.35378/gujs.1240178.
ISNAD Topuz, Muhammet vd. “An Investigation of the Chemical Composition of Bottom Sediments from Dried Lake Gavur of Turkiye by Using XRF and Multivariate Data Analysis”. Gazi University Journal of Science 37/2 (t.y.), 793-811. https://doi.org/10.35378/gujs.1240178.
JAMA Topuz M, Keskin M, Karabulut M, Karlıoğlu Kılıç N. An Investigation of the Chemical Composition of Bottom Sediments from Dried Lake Gavur of Turkiye by Using XRF and Multivariate Data Analysis. Gazi University Journal of Science.;37:793–811.
MLA Topuz, Muhammet vd. “An Investigation of the Chemical Composition of Bottom Sediments from Dried Lake Gavur of Turkiye by Using XRF and Multivariate Data Analysis”. Gazi University Journal of Science, c. 37, sy. 2, ss. 793-11, doi:10.35378/gujs.1240178.
Vancouver Topuz M, Keskin M, Karabulut M, Karlıoğlu Kılıç N. An Investigation of the Chemical Composition of Bottom Sediments from Dried Lake Gavur of Turkiye by Using XRF and Multivariate Data Analysis. Gazi University Journal of Science. 37(2):793-811.