Araştırma Makalesi
Yıl 2018,
Cilt: 30 Sayı: 2, 121 - 126, 19.09.2018
Öz
Bu çalışmada, reflüks yöntemle
hazırlanan mangan oksit ile parasetamol giderimi sabit yataklı kolon reaktörde incelenmiştir.
Parasetamol giderimi üzerine besleme akış hızı, başlangıç parasetamol
konsantrasyonu ve adsorbent dozajı gibi parametrelerinin etkisi araştırılmıştır.
4.8 mL/dk akış hızı, 100 mg/L parasetamol konsantrasyonu ve 1 g adsorbent
dozajı kullanıldığında toplam adsorplanmış parasetamol miktarı 68.0 mg olarak
tespit edilmiştir.
Anahtar Kelimeler
Farmasotik bileşikler parasetamol sabit yataklı kolon reaktör mangan oksit
Kaynakça
- 1. Li, J., Ye, Q., Gan, J. (2014). Degradation and transformation products of acetaminophen in soil. Water Research, 49:44-52. 2. De Laurentiis, E., Prasse, C., Ternes, T. A., Minella, M., Maurino, V., Minero, C., Sarakha, M., Brigante, M., Vione, D. (2014). Assessing the photochemical transformation pathways of acetaminophen relevant to surface waters: Transformation kinetics, intermediates,and modelling. Water Research, 53: 235-248. 3. Carrasco-Díaz, M.R., Castillejos-López, E., Cerpa-Naranjo, A., Rojas-Cervantes, M.L. (2016). Efficient removal of paracetamol using LaCu1_xMxO3 (M = Mn, Ti) perovskites as heterogeneous Fenton-like catalysts. Chemical Engineering Journal, 304: 408-418. 4. Trovό, A.G., Pupo Nogueira, R.F., Aguera, A., Fernandez-Alba, A.R., Malato, S. (2012). Paracetamol degradation intermediates and toxicity during photo-Fenton treatment using different iron species. Water Research, 46: 5374-5380. 5. Brillas, E., Sires, I., Arias, C., Cabot, P.L., Centellas, F., Rodrıguez, R.M., Garrido, J.A. (2005). Mineralization of paracetamol in aqueous medium by anodic oxidation with a boron-doped diamond electrode. Chemosphere, 58: 399–406. 6. García-Mateos, F.J., Ruiz-Rosas, R., Marqués, M.D., Cotoruelo, L.M., Rodríguez-Mirasol, J., Cordero, T. (2015). Removal of paracetamol on biomass-derived activated carbon: Modeling the fixed bed breakthrough curves using batch adsorption experiments. Chemical Engineering Journal. 279: 18–30. 7. Chaudhry, S.A., Khan, T.A., Ali, I. (2017). Equilibrium, kinetic and thermodynamic studies of Cr(VI) adsorption from aqueous solution onto manganese oxide coated sand grain (MOCSG). Journal of Molecular Liquids, 236: 320–330. 8. Ocinski, D., Jacukowicz-Sobala, I., Mazur, P., Raczyk, J., Kociołek-Balawejder, E. (2016). Water treatment residuals containing iron and manganese oxides for arsenic removal from water – Characterization of physicochemical properties and adsorption studies. Chemical Engineering Journal, 294: 210–221. 9. Ahn, M.-S., Ahmad, R., Yoo, J.-Y., Hahn, Y.-B. (2018). Synthesis of manganese oxide nanorods and its application for potassium ion sensing in water. Journal of Colloid and Interface Science, 516: 364–370. 10. Tebo, B.M., Bargar,. J.R., Clement, B.G., Dick, G.J., Murray, K.J., Parker, D., Verity, R., Webb, S.M. (2004). Biogenic manganese oxides: Properties and mechanisms of formation. Annual Reviews of Earth and Planetary Science, 32: 287–328. 11. Tebo, B.M.,Ghiorse, W.C., vanWaasbergen, L.G., Siering, P.L., Caspi, R. (1997). Bacterially mediated mineral formation: Insights into manganese(II) oxidation from molecular genetic and biochemical studies. Geomicrobiology: Interactions Between Microbes and Minerals, Banfield, J.F. and Nealson, K.H., Eds., Mineralogical Society of America, Washington, D.C., p. 225. 12. Zeiner, C.A., Lion, L.W., Shuler, M.L.,Ghirose, W.C., Hay, A. (2006). Cycling of biogenic Mn-oxides in a model microbial predator-prey system. Geomicrobiology Journal, 23: 37-43. 13. Forrez, I., Carballa, M., Verbeken, K.,Vanhaecke, L., Schlüsener, M., Ternes, T., Boon, N., Verstraete, W. (2010). Diclofenac oxidation by biogenic manganese oxides. Environmental Science and Technology, 44: 3449-3454. 14. Samarghandi, M.R., Al-Musawi, T.J., Mohseni-Bandpi, A., Zarrabi, M. (2015). Adsorption of cephalexin from aqueous solution using natural zeolite and zeolite coated with manganese oxide nanoparticles. Journal of Molecular Liquids, 211: 431–441. 15. Abdolali, A., Ngo, H.H., Guo, W., Zhou, J.L., Zhang, J., Liang, S., Chang, S.W., Nguyen, D.D., Liu, Y. (2017). Application of a breakthrough biosorbent for removing heavy metals from synthetic and real wastewaters in a lab-scale continuous fixed-bed column. Bioresource Technology, 229: 78–87. 16. Duan, L., Sun, B., Wei, M., Luo, S., Pan, F., Xu, A., Li, X. (2015). Catalytic degradation of Acid Orange 7 by manganese oxide octahedral molecular sieves with peroxymonosulfate under visible light irradiation. Journal of Hazardous Materials, 285: 356–365. 17. Aksu, Z., Çağatay, Ş.Ş., Gönen, F. (2007). Continuous fixed bed biosorption of reactive dyes by dried Rhizopus arrhizus: Determination of column capacity. Journal of Hazardous Materials, 143: 362–371. 18. Aksu, Z., Gönen, F. (2004). Biosorption of phenol by immobilized activated sludge in a continuous packed bed: prediction of breakthrough curves. Process Biochemistry, 39: 599–613. 19. Bhaumik, M., Setshedi, K., Maity, A., Onyango, M.S. (2013). Chromium(VI) removal from water using fixedbed column ofpolypyrrole/Fe 3O4 nanocomposite. Separation and Purification Technology, 110: 11–19. 20. Nazari, G., Abolghasemi, H., Esmaieli, M., Pouya, E.S. (2016). Aqueous phase adsorption of cephalexin by walnut shell-basedactivated carbon: A fixed-bed column study. Applied Surface Science, 375: 144–153. 21. Smaranda, C., Popescu, M.-C., Bulgariu, D., Malutan, T., Gavrilescu, M. (2017). Adsorption of organic pollutants onto a Romanian soil: Column dynamics and transport. Process Safety and Environmental Protection 108: 108–120. 22. Koçyiğit, H. (1999). Sulardaki kadmiyum kirliliğinin dolgulu kolonlarda adsorpsiyon yolu ile giderilmesi. Yüksek Lisans Tezi, Gazi Üniversitesi Fen Bilimleri Enstitüsü, Ankara. 23. Malkoç, E., Nuhoğlu, Y. (2006). Palamut meşesi (quercus ithaburensis) atığı ile sabit yataklı kolonda Cr(VI) biyosorpsiyonu. DEÜ Mühendislik Fakültesi Fen ve Mühendislik Dergisi, 8(2): 31-45.
Toplam 1 adet kaynakça vardır.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Bölüm | MBD |
| Yazarlar | |
| Yayımlanma Tarihi | 19 Eylül 2018 |
| Gönderilme Tarihi | 9 Şubat 2018 |
| Yayımlandığı Sayı | Yıl 2018 Cilt: 30 Sayı: 2 |