Öz
Bu çalışmada, mermer atıkları katalizörlüğünde haşhaş yağı ve metanolden, transesterifikasyon tepkimesi ile biyodizel üretimi incelenmiştir. Katalizör olarak kullanılan CaO, toz haline getirilen mermer atıklarının 850 °C’de 3 saat süresince kalsinasyonu ile hazırlanmıştır (verim %43) ve XRD ve SEM-EDX yöntemleri ile karakterize edilmiştir. Biyodizel verimine metanol-yağ molar oranı, katalizör miktarı, tepkime süresi ve sıcaklığın etkisi incelenmiş, bu parametrelerin optimum değerleri sırası ile 6:1, %1, 120 dakika ve 65 °C olarak belirlenmiştir. Elde edilen biyodizelin yakıt özelikleri TS EN 14214 standardı ile karşılaştırılarak belirlenmiş ve dizel yakıt ile karıştırılarak kullanılabileceği öngörülmüştür.
Anahtar Kelimeler
Atık Mermer Biyodizel CaO Heterojen kataliz Transesterifikasyon Haşhaş yağı
Destekleyen Kurum
AFYON KOCATEPE ÜNİVERİSTESİ
Proje Numarası
15.FEN.BİL..08
Kaynakça
- Aygün A., 2009. Hint Yağından Biyodizel Eldesi. Yüksek Lisans Tezi, İstanbul Teknik Üniversitesi Fen Bilimleri Enstitüsü, İstanbul.
- Benjapornkulaphong, S., Ngamcharussrivichai,C., and Bunyakiat, K., 2009. Al2O3-Supported alkali and alkali earth metal oxides for transesterification of palm kernel oil and coconut oil. Chemical Engineering Journal, 145, 468–474.
- Boz, N., and Kara, M., 2009. Solid base transesterification of canola oil. Chemical Engineering Communications, 196, 80–92.
- Dönmez, G., 2011. Maya ve Fungus Lipitlerinin Soxhlet Sistemi ile Ekstraksiyonu. Ankara Üniversitesi Bilimsel Arastırma Projeleri Kesin Raporu 10H4240001, Ankara.
- Fukuda, H., Kondo, A. and Noda, H., 2001. Biodiesel fuel production by transesterification of oils. Journal of Bioscience and Bioengineering, 92, 405–416.
- Helwani, Z., Othman, M.R,. Aziz, N., Fernveo, W.J.N. and Kim, J., 2009. Technologies for production of biodiesel focusing on green catalytic techniques: A rewiew. Fuel Processing Technology, 90, 1502-1504.
- Ilgen, O., 2012. Transesterification of canola oil using Marble Dust as a Heterojen. Energy Sources Part A-Recovery Utilization And Environmental Effects. 34, 1688-1694.
- Karaşahin, M., and Terzi, S., 2007. Evaluation of marble waste dust in the mixture of asphaltic concrete. Construction and Building Materials, 21, 616-620.
- Knothe G., 2010. Biodiesel and renewable diesel: A comparison. Prog Energy Combust Sci, 36, 364-373.
- Kouzu M. and Hidaka J., 2012. “Transesterification of vegetable oil into biodiesel catalyzed by CaO.” Fuel, 93, 1-12.
- Lin, C.Y., Lin, H.A. and Hung, L.B., 2006. Fuel structure and properties of biodiesel produced by the peroxidation process. Fuel, 85, 1743–1749,.
- Liu X., He H. and Wang Y., 2008. Transesterification of soybean oil to biodiesel using CaO as a solid base catalyst. Fuel, 8, 216-221.
- Lynd, L.R., 1996. Overview and evaluation of fuel ethanol from cellulosic biomass: technology, economics, the environment, and policy. Annu. Rev. Energy Environ., 21, 403-465,.
- Mittelbach, M. and Remschmidt, C., 2006. Biodiesel: the comprehensive handbook (third edition). Martin Mittelbach, Graz, Austria.
- Schuchardt U., Sercheli R. ve Vargas R. M., 1998. Transesterification of vegetable oils: A review. Journal of Brazil Chemical Society, 9, 199-210.
- Tangboriboon, N., Kunanuruksapong, R., and Sirivat A., 2012. Preparation and properties of calcium oxide from eggshells via calcination. Materials Science-Poland, 30, 313-322.
- Topçu, I. B., Bilir, T., and Uygunoğlu, T., 2009. Effect of waste marble dust content as filler on properties of self-compacting concrete. Construction and Building Materials, 23, 1947–1953.
Öz
In this study, biodiesel production from poppy oil and methanol, by transesterification reaction, was investigated by using waste marble dust as catalyst. The CaO, used as catalyst, was prepared (yield 43%) by calcination of powdered marble dust at 850 °C for 3 h and characterized by XRD and SEM-EDX techniques. The effects of methanol: oil molar ratio, catalyst amount, reaction time and temperature on the biodiesel yield were investigated and optimum values of these parameters were determined as 6:1, 1%, 120 min and 65°C, respectively. The properties of the produced biodiesel were determined by compared with TS EN 14214 standard and it is expected to use with diesel.
Anahtar Kelimeler
Marble Dust Biodiesel CaO Heterogeneous Catalysis Transesterification reaction Poppy Oil
Proje Numarası
15.FEN.BİL..08
Kaynakça
- Aygün A., 2009. Hint Yağından Biyodizel Eldesi. Yüksek Lisans Tezi, İstanbul Teknik Üniversitesi Fen Bilimleri Enstitüsü, İstanbul.
- Benjapornkulaphong, S., Ngamcharussrivichai,C., and Bunyakiat, K., 2009. Al2O3-Supported alkali and alkali earth metal oxides for transesterification of palm kernel oil and coconut oil. Chemical Engineering Journal, 145, 468–474.
- Boz, N., and Kara, M., 2009. Solid base transesterification of canola oil. Chemical Engineering Communications, 196, 80–92.
- Dönmez, G., 2011. Maya ve Fungus Lipitlerinin Soxhlet Sistemi ile Ekstraksiyonu. Ankara Üniversitesi Bilimsel Arastırma Projeleri Kesin Raporu 10H4240001, Ankara.
- Fukuda, H., Kondo, A. and Noda, H., 2001. Biodiesel fuel production by transesterification of oils. Journal of Bioscience and Bioengineering, 92, 405–416.
- Helwani, Z., Othman, M.R,. Aziz, N., Fernveo, W.J.N. and Kim, J., 2009. Technologies for production of biodiesel focusing on green catalytic techniques: A rewiew. Fuel Processing Technology, 90, 1502-1504.
- Ilgen, O., 2012. Transesterification of canola oil using Marble Dust as a Heterojen. Energy Sources Part A-Recovery Utilization And Environmental Effects. 34, 1688-1694.
- Karaşahin, M., and Terzi, S., 2007. Evaluation of marble waste dust in the mixture of asphaltic concrete. Construction and Building Materials, 21, 616-620.
- Knothe G., 2010. Biodiesel and renewable diesel: A comparison. Prog Energy Combust Sci, 36, 364-373.
- Kouzu M. and Hidaka J., 2012. “Transesterification of vegetable oil into biodiesel catalyzed by CaO.” Fuel, 93, 1-12.
- Lin, C.Y., Lin, H.A. and Hung, L.B., 2006. Fuel structure and properties of biodiesel produced by the peroxidation process. Fuel, 85, 1743–1749,.
- Liu X., He H. and Wang Y., 2008. Transesterification of soybean oil to biodiesel using CaO as a solid base catalyst. Fuel, 8, 216-221.
- Lynd, L.R., 1996. Overview and evaluation of fuel ethanol from cellulosic biomass: technology, economics, the environment, and policy. Annu. Rev. Energy Environ., 21, 403-465,.
- Mittelbach, M. and Remschmidt, C., 2006. Biodiesel: the comprehensive handbook (third edition). Martin Mittelbach, Graz, Austria.
- Schuchardt U., Sercheli R. ve Vargas R. M., 1998. Transesterification of vegetable oils: A review. Journal of Brazil Chemical Society, 9, 199-210.
- Tangboriboon, N., Kunanuruksapong, R., and Sirivat A., 2012. Preparation and properties of calcium oxide from eggshells via calcination. Materials Science-Poland, 30, 313-322.
- Topçu, I. B., Bilir, T., and Uygunoğlu, T., 2009. Effect of waste marble dust content as filler on properties of self-compacting concrete. Construction and Building Materials, 23, 1947–1953.
Ayrıntılar
| Birincil Dil | Türkçe |
|---|---|
| Konular | Mühendislik |
| Bölüm | Makaleler |
| Yazarlar | |
| Proje Numarası | 15.FEN.BİL..08 |
| Yayımlanma Tarihi | 30 Kasım 2020 |
| Gönderilme Tarihi | 2 Nisan 2020 |
| Yayımlandığı Sayı | Yıl 2020 Cilt: 20 Sayı: 5 |
