Research Article
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Improvement of Mechanical and Corrosive Properties of Epoxy Coatings by Addition of Nanozinc Oxide Particles

Year 2023, Volume: 28 Issue: 1, 11 - 24, 30.04.2023

Mehmet Kubilay Askerden Ahmet Akdemir Fazliye Karabörk Şakir Yazman

https://doi.org/10.17482/uumfd.1204841

Abstract

In this study, the effect of ZnO nanoparticles added to the epoxy coating used to protect metal surfaces on the mechanical and anticorrosive properties of the coating was investigated. The study was carried out in two stages. In the first stage, studies were carried out both to produce the composite material by determining the amount of particles to be added and to determine the properties of this material. As a result of the experimental studies, it was decided to add nano ZnO to the epoxy matrix at 0.5%, 1 and 1.5% by weight. At the end of the tensile test applied to the composite materials prepared with these ratios, the highest properties were obtained in the composite material with 1% ZnO nanoparticles by weight. In order to determine other properties of nanocomposites; DSC, TGA, FTIR, SEM analyzes were made. In the second step, the prepared nanocomposites were coated on steel test plates. The anticorrosive performance of the coatings was investigated by acid solution immersion and salt fog tests. According to the corrosion test results, the best result was obtained in the composite coating with 1% ZnO nanoparticles. In addition, the impact resistance, flexibility and adhesion properties of the coatings to the steel substrate were investigated by various tests.

Keywords

Nanocomposite coating ZnO Nanoparticle Impact Adhesion Corrosion

References

  • 1. Abaci, S., Nessark, B. (2015) Characterization and corrosion protection properties of composite material (PANI+TiO2) coatings on A304 stainless steel, Journal of Coatings Technology and Research, 12, 107-120. doi: 10.1007/s11998-014-9611-x
  • 2. Apsak, M., Akdemir, A., Karabörk, F., Yazman, Ş. (2021) Investigation Effect of Zinc Nanoparticles on The Mechanical and Anticorrosion Properties of Epoxy Coatings on Stainless Steel Surface, Gazi University Journal of Science, 34(3), 846-877. doi: 10.35378/gujs.760830
  • 3. Avella M., Errico M.E., Martelli S. ve Martuscelli E. (2001) Preparation methodologies of polymer matrix nanocomposites, Applied Organometallic Chemistry, 15, 434-439. doi: 10.1002/aoc.168
  • 4. Baig M. M. A. ve Abdul Samad M. (2021) Epoxy / Epoxy Composite / Epoxy Hybrid Composite Coatings for Tribological Applications—A Review, Polymers, 13, 179. doi: 10.3390/polym13020179
  • 5. Barletta, M., Vesco, S., Puopolo, M. ve Tagliaferri, V. (2016) Graphene reinforced UV-curable epoxy resins: Design, manufacture and material performance, Progress in Organic Coatings, 90, 414-424. doi: 10.1016/j.porgcoat.2015.08.013
  • 6. Behzadnasab, M., Mirabedini, S.M., Kabiri, K. ve Jamali S. (2011) Corrosion performance of epoxy coatings containing silane treated ZrO2 nanoparticles on mild steel in 3.5% NaCl solution, Corrosion Science, 53, 89-98. doi: 10.1016/j.corsci.2010.09.026
  • 7. Boumaza, M., Khan, R. ve Zahrani, S. (2016) An experimental investigation of the effects of nanoparticles on the mechanical properties of epoxy coating, Thin Solid Films, 620, 160-164. doi: 10.1016/j.tsf.2016.09.035
  • 8. Conradi, M., Intihar, G. ve Milena Zorko, M. (2015) Mechanical and wetting properties of nanosilica/epoxy-coated stainless steel, Materials and technology, 49(4), 613–618. doi: 10.17222/mit.2015.060
  • 9. Dhoke S.K. ve Khanna A.S. (2009) Electrochemical behavior of nano-iron oxide modified alkyd based waterborne coatings, Materials Chemistry and Physics, 117, 550-556. doi: 10.1016/j.matchemphys.2009.07.010
  • 10. Ghanbari, A. ve Attar, M.M. (2015) A study on the anticorrosion performance of epoxy nanocomposite coatings containing epoxy-silane treated nano-silica on mild steel substrate, Journal of Industrial and Engineering Chemistry, 23, 145-153. doi: 10.1016/j.jiec.2014.08.008
  • 11. Haeri, S.Z., Ramezanzadeh, B., Asghari, M., Barletta ve diğ. (2016) A novel fabrication of a high performance SiO2-grapheneoxide (GO) nanohybrids: Characterization of thermal properties of epoxy nanocomposites filled with SiO2–GO nanohybrids, Journal of Colloid and Interface Science, 493, 111-122. doi: 10.1016/j.jcis.2017.01.016
  • 12. Hussain, A. K., Seetharamaiah, N., Pichumani, M., Chakra C. S. (2021) Research progress in organic zinc rich primer coatings for cathodic protection of metals – A comprehensive review, Progress in Organic Coatings, 153, 106040. doi: 10.1016/j.porgcoat.2020.106040
  • 13. Jiang, T., Kuila, Y., Kim, N.H., Ku, B.C. ve Lee, J.H. (2013) Enhanced mechanical properties of silanized silica nanoparticle attached graphene oxide/epoxy composites, Composites Science Technology, 79, 115-125. doi: 10.1016/j.compscitech.2013.02.018
  • 14. Khun, N.W., RinconTroconis, B.C., Frankel, G.S. (2014) Effects of carbonnanotube content on adhesion strength and wear and corrosion resistance of epoxy composite coatings on AA2024- T3, Progress in Organic Coatings, 77, 72-80. doi: 10.1016/j.porgcoat.2013.08.003
  • 15. Kouloumbi, N. ve Moundoulas, P. (2002) Anticorrosive performance of organic coatings on steel surfaces exposed to deionized water, Pigment & Resin Technology, 31(2), 74-83. doi: 10.1108/03699420210420350
  • 16. Mobin, M., Aslam, J., Alam, R. (2017) Corrosion protection of poly(aniline-co-N-ethylaniline)/ZnO nanocomposite coating on mild steel, Arabian Journal for Science and Engineering, 42, 209-224. doi: 10.1007/s13369-016-2234-z
  • 17. Mostafaei, A., Nasirpouri, F. (2014) Epoxy/polyaniline–ZnO nanorods hybrid nanocomposite coatings, Synthesis, characterization and corrosion protection performance of conducting paints, Progress in Organic Coatings, 77(1), 146-159. doi: 10.1016/j.porgcoat.2013.08.015
  • 18. Ozcan, U.E., Karabork, F., Yazman, S., Akdemir, A. (2019) Effect of Silica/Graphene Nanohybrid Particles on the Mechanical Properties of Epoxy Coatings, Arabian Journal for Science and Engineering, 44, 5723-5731. doi: 10.1007/s13369-019-03724-x
  • 19. Ramezanzadeh, B. ve Attar, M.M. (2011) Characterization of the fracture behavior and viscoelastic properties of epoxy polyamide coating reinforced with nanometer and micrometer sized ZnO particles, Progress in Organic Coatings, 71, 242-249. doi: 10.1016/j.porgcoat.2011.03.004
  • 20. Ramezanzadeh, B., Moradian, S., Tahmasebi, N. ve Khosravi, A. (2011) Studying the role of polysiloxane additives and nano-SiO2 on the mechanical properties of a typical acrylic/melamine clearcoat, Progress in Organic Coatings, 72(4), 621-631. doi: 10.1016/j.porgcoat.2011.07.003
  • 21. Rong M.Z., Zhang M.Q., Liu H., Zeng H.M., Wetzel B. ve Friedrich K. (2001) Microstructure and tribological behavior of polymeric nanocomposites, Industrial Lubrication and Tribology, 53(2), 72-79. doi: 10.1108/00368790110383993
  • 22. Shaik M.R., Alam M., Alandis N.M. (2015) Development of sustainable resource based poly(urethane-etheramide)/Fe2O3 nanocomposite as anticorrosive coating materials, Journal of Polymer Engineering, 35(9), 905-916. doi: 10.1515/polyeng-2015-0009
  • 23. Shi, X., Nguyen, T.A., Suo, Z., Liu, Y. ve Avci, R. (2009) Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating, Surface & Coatings Technology, 204, 237-245. doi: 10.1016/j.surfcoat.2009.06.048
  • 24. Wetzel, B., Haupert, F. ve Zhang M.Q. (2003) Epoxy nanocomposites with high mechanical and tribological performance, Composites Science and Technology, 63, 2055-2067. doi: 10.1016/S0266-3538(03)00115-5
  • 25. Zhang M., Wang H., Nie T., Bai J., Zhao F. ve Ma S. (2020) Enhancement of barrier and anti-corrosive performance of zinc-rich epoxy coatings using nano-silica/graphene oxide hybrid, Corrosion Reviews, 38(6), 497-513 doi: 10.1515/corrrev-2020-0034
  • 26. Zhang, M.Q., Rong, M.Z., Yu, S.L., Wetzel, B. ve Friedrcih, K. (2002) Improvement of the tribological performance of epoxy by the addition of irradiation grafted nano-inorganic particles, Macromolecular Materials Engineering, 287, 111-115. doi: 10.1002/1439-2054(20020201)287:2<111::AID-MAME111>3.0.CO;2-I

NANO ÇİNKO OKSİT PARTİKÜL KATILAN EPOKSİ KAPLAMALARIN MEKANİK VE ANTİKOROZİF ÖZELLİKLERİNİN İNCELENMESİ

Year 2023, Volume: 28 Issue: 1, 11 - 24, 30.04.2023

Mehmet Kubilay Askerden Ahmet Akdemir Fazliye Karabörk Şakir Yazman

https://doi.org/10.17482/uumfd.1204841

Abstract

Bu çalışmada, metal yüzeyleri korumak amacıyla kullanılan epoksi kaplamaya katılan ZnO nanopartiküllerin kaplamanın mekanik ve antikorozif özellikleri üzerindeki etkisi araştırılmıştır. Çalışma iki aşamada gerçekleştirilmiştir. İlk aşamada hem katılacak partikül miktarını belirleyerek kompozit malzemeyi üretmek hem de bu malzemenin özelliklerini belirlemek için çalışmalar yapılmıştır. Deneysel çalışmalar sonucunda epoksi matrise ağ. %0,5, 1 ve 1,5 oranlarında nano ZnO katılmasına karar verilmiştir. Bu oranlarla hazırlanan kompozit malzemelere uygulanan çekme testi sonunda en yüksek özellikler ağ. %1 ZnO nanopartikül katılan kompozit malzemede elde edilmiştir. Nanokompozitlerin diğer özelliklerini belirlemek amacıyla ayrıca; DSC, TGA, FTIR, SEM analizleri yapılmıştır. İkinci aşamada hazırlanan nanokompozitler çelik test plakaları üzerine kaplanmıştır. Kaplamaların antikorozif performansı asit çözeltisine daldırma ve tuz sisi testleri ile incelenmiştir. Korozyon testi sonuçlarına göre, en iyi sonuç %1 ZnO nanopartikül katılan kompozit kaplamada elde edilmiştir. Ayrıca kaplamaların darbe dayanımı, esnekliği ve çelik alt tabakaya yapışma özellikleri çeşitli testlerle incelenmiştir.

Keywords

Nanokompozit kaplama ZnO nanopartikül darbe adezyon korozyon

References

  • 1. Abaci, S., Nessark, B. (2015) Characterization and corrosion protection properties of composite material (PANI+TiO2) coatings on A304 stainless steel, Journal of Coatings Technology and Research, 12, 107-120. doi: 10.1007/s11998-014-9611-x
  • 2. Apsak, M., Akdemir, A., Karabörk, F., Yazman, Ş. (2021) Investigation Effect of Zinc Nanoparticles on The Mechanical and Anticorrosion Properties of Epoxy Coatings on Stainless Steel Surface, Gazi University Journal of Science, 34(3), 846-877. doi: 10.35378/gujs.760830
  • 3. Avella M., Errico M.E., Martelli S. ve Martuscelli E. (2001) Preparation methodologies of polymer matrix nanocomposites, Applied Organometallic Chemistry, 15, 434-439. doi: 10.1002/aoc.168
  • 4. Baig M. M. A. ve Abdul Samad M. (2021) Epoxy / Epoxy Composite / Epoxy Hybrid Composite Coatings for Tribological Applications—A Review, Polymers, 13, 179. doi: 10.3390/polym13020179
  • 5. Barletta, M., Vesco, S., Puopolo, M. ve Tagliaferri, V. (2016) Graphene reinforced UV-curable epoxy resins: Design, manufacture and material performance, Progress in Organic Coatings, 90, 414-424. doi: 10.1016/j.porgcoat.2015.08.013
  • 6. Behzadnasab, M., Mirabedini, S.M., Kabiri, K. ve Jamali S. (2011) Corrosion performance of epoxy coatings containing silane treated ZrO2 nanoparticles on mild steel in 3.5% NaCl solution, Corrosion Science, 53, 89-98. doi: 10.1016/j.corsci.2010.09.026
  • 7. Boumaza, M., Khan, R. ve Zahrani, S. (2016) An experimental investigation of the effects of nanoparticles on the mechanical properties of epoxy coating, Thin Solid Films, 620, 160-164. doi: 10.1016/j.tsf.2016.09.035
  • 8. Conradi, M., Intihar, G. ve Milena Zorko, M. (2015) Mechanical and wetting properties of nanosilica/epoxy-coated stainless steel, Materials and technology, 49(4), 613–618. doi: 10.17222/mit.2015.060
  • 9. Dhoke S.K. ve Khanna A.S. (2009) Electrochemical behavior of nano-iron oxide modified alkyd based waterborne coatings, Materials Chemistry and Physics, 117, 550-556. doi: 10.1016/j.matchemphys.2009.07.010
  • 10. Ghanbari, A. ve Attar, M.M. (2015) A study on the anticorrosion performance of epoxy nanocomposite coatings containing epoxy-silane treated nano-silica on mild steel substrate, Journal of Industrial and Engineering Chemistry, 23, 145-153. doi: 10.1016/j.jiec.2014.08.008
  • 11. Haeri, S.Z., Ramezanzadeh, B., Asghari, M., Barletta ve diğ. (2016) A novel fabrication of a high performance SiO2-grapheneoxide (GO) nanohybrids: Characterization of thermal properties of epoxy nanocomposites filled with SiO2–GO nanohybrids, Journal of Colloid and Interface Science, 493, 111-122. doi: 10.1016/j.jcis.2017.01.016
  • 12. Hussain, A. K., Seetharamaiah, N., Pichumani, M., Chakra C. S. (2021) Research progress in organic zinc rich primer coatings for cathodic protection of metals – A comprehensive review, Progress in Organic Coatings, 153, 106040. doi: 10.1016/j.porgcoat.2020.106040
  • 13. Jiang, T., Kuila, Y., Kim, N.H., Ku, B.C. ve Lee, J.H. (2013) Enhanced mechanical properties of silanized silica nanoparticle attached graphene oxide/epoxy composites, Composites Science Technology, 79, 115-125. doi: 10.1016/j.compscitech.2013.02.018
  • 14. Khun, N.W., RinconTroconis, B.C., Frankel, G.S. (2014) Effects of carbonnanotube content on adhesion strength and wear and corrosion resistance of epoxy composite coatings on AA2024- T3, Progress in Organic Coatings, 77, 72-80. doi: 10.1016/j.porgcoat.2013.08.003
  • 15. Kouloumbi, N. ve Moundoulas, P. (2002) Anticorrosive performance of organic coatings on steel surfaces exposed to deionized water, Pigment & Resin Technology, 31(2), 74-83. doi: 10.1108/03699420210420350
  • 16. Mobin, M., Aslam, J., Alam, R. (2017) Corrosion protection of poly(aniline-co-N-ethylaniline)/ZnO nanocomposite coating on mild steel, Arabian Journal for Science and Engineering, 42, 209-224. doi: 10.1007/s13369-016-2234-z
  • 17. Mostafaei, A., Nasirpouri, F. (2014) Epoxy/polyaniline–ZnO nanorods hybrid nanocomposite coatings, Synthesis, characterization and corrosion protection performance of conducting paints, Progress in Organic Coatings, 77(1), 146-159. doi: 10.1016/j.porgcoat.2013.08.015
  • 18. Ozcan, U.E., Karabork, F., Yazman, S., Akdemir, A. (2019) Effect of Silica/Graphene Nanohybrid Particles on the Mechanical Properties of Epoxy Coatings, Arabian Journal for Science and Engineering, 44, 5723-5731. doi: 10.1007/s13369-019-03724-x
  • 19. Ramezanzadeh, B. ve Attar, M.M. (2011) Characterization of the fracture behavior and viscoelastic properties of epoxy polyamide coating reinforced with nanometer and micrometer sized ZnO particles, Progress in Organic Coatings, 71, 242-249. doi: 10.1016/j.porgcoat.2011.03.004
  • 20. Ramezanzadeh, B., Moradian, S., Tahmasebi, N. ve Khosravi, A. (2011) Studying the role of polysiloxane additives and nano-SiO2 on the mechanical properties of a typical acrylic/melamine clearcoat, Progress in Organic Coatings, 72(4), 621-631. doi: 10.1016/j.porgcoat.2011.07.003
  • 21. Rong M.Z., Zhang M.Q., Liu H., Zeng H.M., Wetzel B. ve Friedrich K. (2001) Microstructure and tribological behavior of polymeric nanocomposites, Industrial Lubrication and Tribology, 53(2), 72-79. doi: 10.1108/00368790110383993
  • 22. Shaik M.R., Alam M., Alandis N.M. (2015) Development of sustainable resource based poly(urethane-etheramide)/Fe2O3 nanocomposite as anticorrosive coating materials, Journal of Polymer Engineering, 35(9), 905-916. doi: 10.1515/polyeng-2015-0009
  • 23. Shi, X., Nguyen, T.A., Suo, Z., Liu, Y. ve Avci, R. (2009) Effect of nanoparticles on the anticorrosion and mechanical properties of epoxy coating, Surface & Coatings Technology, 204, 237-245. doi: 10.1016/j.surfcoat.2009.06.048
  • 24. Wetzel, B., Haupert, F. ve Zhang M.Q. (2003) Epoxy nanocomposites with high mechanical and tribological performance, Composites Science and Technology, 63, 2055-2067. doi: 10.1016/S0266-3538(03)00115-5
  • 25. Zhang M., Wang H., Nie T., Bai J., Zhao F. ve Ma S. (2020) Enhancement of barrier and anti-corrosive performance of zinc-rich epoxy coatings using nano-silica/graphene oxide hybrid, Corrosion Reviews, 38(6), 497-513 doi: 10.1515/corrrev-2020-0034
  • 26. Zhang, M.Q., Rong, M.Z., Yu, S.L., Wetzel, B. ve Friedrcih, K. (2002) Improvement of the tribological performance of epoxy by the addition of irradiation grafted nano-inorganic particles, Macromolecular Materials Engineering, 287, 111-115. doi: 10.1002/1439-2054(20020201)287:2<111::AID-MAME111>3.0.CO;2-I
There are 26 citations in total.

Details

Primary Language Turkish
Subjects Mechanical Engineering, Nanotechnology
Journal Section Research Articles
Authors

Mehmet Kubilay Askerden 0000-0003-3883-7300

Ahmet Akdemir 0000-0002-8791-8847

Fazliye Karabörk 0000-0002-2304-7034

Şakir Yazman 0000-0002-4064-0024

Publication Date April 30, 2023
Submission Date November 15, 2022
Acceptance Date March 14, 2023
Published in Issue Year 2023 Volume: 28 Issue: 1

Cite

APA Askerden, M. K., Akdemir, A., Karabörk, F., Yazman, Ş. (2023). NANO ÇİNKO OKSİT PARTİKÜL KATILAN EPOKSİ KAPLAMALARIN MEKANİK VE ANTİKOROZİF ÖZELLİKLERİNİN İNCELENMESİ. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, 28(1), 11-24. https://doi.org/10.17482/uumfd.1204841
AMA Askerden MK, Akdemir A, Karabörk F, Yazman Ş. NANO ÇİNKO OKSİT PARTİKÜL KATILAN EPOKSİ KAPLAMALARIN MEKANİK VE ANTİKOROZİF ÖZELLİKLERİNİN İNCELENMESİ. UUJFE. April 2023;28(1):11-24. doi:10.17482/uumfd.1204841
Chicago Askerden, Mehmet Kubilay, Ahmet Akdemir, Fazliye Karabörk, and Şakir Yazman. “NANO ÇİNKO OKSİT PARTİKÜL KATILAN EPOKSİ KAPLAMALARIN MEKANİK VE ANTİKOROZİF ÖZELLİKLERİNİN İNCELENMESİ”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 28, no. 1 (April 2023): 11-24. https://doi.org/10.17482/uumfd.1204841.
EndNote Askerden MK, Akdemir A, Karabörk F, Yazman Ş (April 1, 2023) NANO ÇİNKO OKSİT PARTİKÜL KATILAN EPOKSİ KAPLAMALARIN MEKANİK VE ANTİKOROZİF ÖZELLİKLERİNİN İNCELENMESİ. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 28 1 11–24.
IEEE M. K. Askerden, A. Akdemir, F. Karabörk, and Ş. Yazman, “NANO ÇİNKO OKSİT PARTİKÜL KATILAN EPOKSİ KAPLAMALARIN MEKANİK VE ANTİKOROZİF ÖZELLİKLERİNİN İNCELENMESİ”, UUJFE, vol. 28, no. 1, pp. 11–24, 2023, doi: 10.17482/uumfd.1204841.
ISNAD Askerden, Mehmet Kubilay et al. “NANO ÇİNKO OKSİT PARTİKÜL KATILAN EPOKSİ KAPLAMALARIN MEKANİK VE ANTİKOROZİF ÖZELLİKLERİNİN İNCELENMESİ”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 28/1 (April 2023), 11-24. https://doi.org/10.17482/uumfd.1204841.
JAMA Askerden MK, Akdemir A, Karabörk F, Yazman Ş. NANO ÇİNKO OKSİT PARTİKÜL KATILAN EPOKSİ KAPLAMALARIN MEKANİK VE ANTİKOROZİF ÖZELLİKLERİNİN İNCELENMESİ. UUJFE. 2023;28:11–24.
MLA Askerden, Mehmet Kubilay et al. “NANO ÇİNKO OKSİT PARTİKÜL KATILAN EPOKSİ KAPLAMALARIN MEKANİK VE ANTİKOROZİF ÖZELLİKLERİNİN İNCELENMESİ”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, vol. 28, no. 1, 2023, pp. 11-24, doi:10.17482/uumfd.1204841.
Vancouver Askerden MK, Akdemir A, Karabörk F, Yazman Ş. NANO ÇİNKO OKSİT PARTİKÜL KATILAN EPOKSİ KAPLAMALARIN MEKANİK VE ANTİKOROZİF ÖZELLİKLERİNİN İNCELENMESİ. UUJFE. 2023;28(1):11-24.

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