Abstract
CaCO3 as a filler has been used in the PVC. In this study, industrial waste was used instead of CaCO3 and were investigated changes in the thermal properties. Used in cutting waste was emerged during the produced in GRP pipe production from wet cutting. PVC, GRP waste powder and process aids were mixtured then produced in extrusion system for polymer matrix composite production. Thirteen different weight (%5-%70) percentages of cutting waste as a filler were reinforced to PVC. CaCO3 reinforced and pure PVC were produced in extrusion system to make comparison. All PVC samples were evaluated through DTA-TG analysis.
Keywords
References
- W. V. Titow, PVC technology, New York, Springer Science & Business Media, 1984, pp. 10-18.
- R. H. Burgess, Manufacture and Processing of PVC, Massachusetts, CRC Press, 1981, pp. 1-174.
- A. E. Avci, "Analysıs Of Uv Induced Dehydrochlorınated Pvc," Doctoral Dissertation, Department of Chemistry and the Institute of Engineering and Science, Bilkent Unıversıty, Ankara, Turkey, 2003.
- L. Nass, Encyclopedia of PVC, Second Edition: Compounding Processes, Product Design and Specifications, New York: CRC Press, 1992.
- L. Gye-Seung. (2007). Recycling EAF dust by heat treatment with PVC. Minerals engineering, 20(8), pp. 739-746.
- L. Saeed. (2004). Pyrolysis and combustion of PVC, PVC-wood and PVC-coal mixtures in a two-stage fluidized bed process. Fuel Processing Technology, 85(14) pp. 1565-1583.
- J. Cazes, Analytical instrumentation handbook, Boca Raton, CRC Press, 2004, pp. 491-503.
- P. V. McKinney. (1967). DTA evidence for physical orientation (crystallinity) in PVC. Journal of Applied Polymer Science, 11(7) pp. 1189-1197.
- M. A. Centeno. (2011). Thermal analysis of monument patina containing hydrated calcium oxalates. Thermochimica Acta, 512(1) pp. 5-12.
Abstract
Bu çalışmada, PVC üretiminde kullanılan CaCO3 dolgu malzemesi yerine, sanayi atığı kullanılması sonucu termal özelliklerdeki değişim araştırılmıştır. Kullanılan sanayi atığı CTP boru üretiminden sulu kesim sırasında çıkmakta ve SiO2, cam elyaf ve polyester reçine içermektedir. Sulu çamur halinde filtre presten çıkan atık fabrikadan alındıktan sonra kurutma ve eleme işlemleri uygulanarak toz formuna getirilmiştir. Numuneler PVC, CTP atık tozu ve prosese yardımcı maddeler mikserde karıştırılarak ekstrüzyon yöntemi ile profil şeklinde üretilmiştir. Atık toz PVC’ye oranla ağırlıkça %5-%70 oranlarında dolgu malzemesi olarak kullanılmıştır. Kalsit (CaCO3) katkılı ve katkısız PVC numuneleri de benzer proses parametreleri kullanılarak üretilmiştir. Üretilen numuneler, seramik krozeler kullanılarak DTA-TG analizleri yapılmıştır.
Keywords
References
- W. V. Titow, PVC technology, New York, Springer Science & Business Media, 1984, pp. 10-18.
- R. H. Burgess, Manufacture and Processing of PVC, Massachusetts, CRC Press, 1981, pp. 1-174.
- A. E. Avci, "Analysıs Of Uv Induced Dehydrochlorınated Pvc," Doctoral Dissertation, Department of Chemistry and the Institute of Engineering and Science, Bilkent Unıversıty, Ankara, Turkey, 2003.
- L. Nass, Encyclopedia of PVC, Second Edition: Compounding Processes, Product Design and Specifications, New York: CRC Press, 1992.
- L. Gye-Seung. (2007). Recycling EAF dust by heat treatment with PVC. Minerals engineering, 20(8), pp. 739-746.
- L. Saeed. (2004). Pyrolysis and combustion of PVC, PVC-wood and PVC-coal mixtures in a two-stage fluidized bed process. Fuel Processing Technology, 85(14) pp. 1565-1583.
- J. Cazes, Analytical instrumentation handbook, Boca Raton, CRC Press, 2004, pp. 491-503.
- P. V. McKinney. (1967). DTA evidence for physical orientation (crystallinity) in PVC. Journal of Applied Polymer Science, 11(7) pp. 1189-1197.
- M. A. Centeno. (2011). Thermal analysis of monument patina containing hydrated calcium oxalates. Thermochimica Acta, 512(1) pp. 5-12.
Details
| Subjects | Engineering |
|---|---|
| Journal Section | Research Articles |
| Authors | |
| Publication Date | August 1, 2016 |
| Submission Date | July 3, 2015 |
| Acceptance Date | October 9, 2015 |
| Published in Issue | Year 2016 Volume: 20 Issue: 2 |
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