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EFFECT of TEMPERAUTRE on PACK SILICONIZING of Ti6Al4V ALLOY

Year 2022, Volume: 3 Issue: 1, 11 - 21, 29.06.2022

Eşref Furkan Tepe Gözde Çelebi Efe Tuba Yener

Abstract

This study aims to investigate the temperature effects on silicide coating formed by pack siliconizing method on Ti6Al4V subsrate. Pack siliconizing process was conducted out for 2h at 1000°C, 1100°C, 1200°C, in vacum atmosphere, by using Si as Si source, Al2O3 powder as filler and NH4Cl as an activator. The presence of the formed phases such as Ti5Si3, TiSi, TiSi2 on coating, and non-stoichiometric Al203 compound from the pack mixture was actualized by X-ray diffraction analysis (XRD). It was obeserved that the silicide coating on Ti6Al4V substrate is compact, dense and the coating thickness varies between 10.5-30.4 μm depending on the treatment temperature. The morphological feautres of the coating and dispersion of the elements in the silicide layer was examined by using electron microscope (SEM) and elemental analysis (EDS). Hardness of silicide layer measured by Vickers method and determined that the hardness ranges between 1170 Hv0,025 to 1450 HV 0,025 .

Keywords

Pack cementation pack siliconizing diffusion coating Ti6Al4V silicide coating

Project Number

2021-50-01-063

References

  • [1] M. Jackson, R.R. Boyer, Titanium and its Alloys: Processing, Fabrication and Mechanical Performance, Encycl. Aerosp. Eng. (2010) 1–16. https://doi.org/10.1002/9780470686652.eae199.
  • [2] R. Boyer, G. Welsch, E.W. Collings, Materials properties handbook : titanium alloys, 1994.
  • [3] K. Chou, P.W. Chu, E.A. Marquis, Early oxidation behavior of Si-coated titanium, Corros. Sci. 140 (2018) 297–306. https://doi.org/10.1016/j.corsci.2018.05.035.
  • [4] M. Hetmańczyk, L. Swadźba, B. Mendala, Advanced materials and protective coatings in aero-engines application co-operating with Manufacturing and processing, 2007. www.journalamme.org.
  • [5] F.J. Pérez, M.P. Hierro, M.C. Carpintero, F.J. Bolivar, Aluminum and silicon co-deposition by the chemical vapor deposition in fluidized bed reactor technique as a precursor of protective coatings of mullite, Surf. Coatings Technol. 184 (2004) 361–369. https://doi.org/10.1016/j.surfcoat.2003.11.001.
  • [6] R. Bianco, R.A. Rapp, Pack cementation diffusion coatings, Metall. Ceram. Prot. Coatings. (1996) 236–260. https://doi.org/10.1007/978-94-009-1501-5_9.
  • [7] T.R. Rautray, R. Narayanan, T. Kwon, K. Kim, Surface Modification of Titanium and Titanium Alloys by Ion Implantation Review Surface Modification of Titanium and Titanium Alloys by Ion Implantation, (2010). https://doi.org/10.1002/jbm.b.31596.
  • [8] A.R. Castle, D.R. Gabe, Chromium diffusion coatings The application of diffusion coatings has become, 1999.
  • [9] W. Yang, J. Park, K. Choi, C.H. Chung, J. Lee, J. Zhu, F. Zhang, J.S. Park, Evaluation of growth kinetics of aluminide coating layers on Ti-6Al-4V alloys by pack cementation and the oxidation behaviours of the coated Ti-6Al-4V alloys, Int. J. Refract. Met. Hard Mater. 101 (2021) 105642. https://doi.org/10.1016/j.ijrmhm.2021.105642.
  • [10] D. Vojtěch, B. Bártová, T. Kubatík, High temperature oxidation of titanium-silicon alloys, Mater. Sci. Eng. A. 361 (2003) 50–57. https://doi.org/10.1016/S0921-5093(03)00564-1.
  • [11] G.Ç. Efe, İ. Altınsoy, T. Yener, M. İpek, C. Bindal, S. Zeytin, Surface Modifi cation of Ti6Al4V Alloy by Pack Siliconizing Method, (2018) 1024–1027.
  • [12] A.E. Kochmańska, A. Jarlaczyńska, J. Baranowska, Formation of silicide and silicide-aluminide coatings on molybdenum alloy during slurry cementation process: Influence of slurry volume, Materials (Basel). 14 (2021). https://doi.org/10.3390/ma14226940.
  • [13] T. Shimozaki, T. Okino, M. Yamane, Y. Wakamatsu, M. Onishi, Effect of impurities on growth of Ti silicides in bulk Ti/Si diffusion couple, Mater. Trans. JIM. 38 (1997) 865–870. ttps://doi.org/10.2320/matertrans1989.38.865.
  • [14] A. Paul, S. Divinski, Handbook of Solid State Diffusion, First edit, Elsevier Inc., 2017.
  • [15] B. Cockeram, G. Wang, The influence of multi-layered kinetics on the selection of the primary phase during the diffusion-controlled growth of titanium-silicide layers, 1995.
  • [16] C.M. Cotell, J.A. Sprague, F.A. Smidt, R. Menezes Nunes UFRGS, R.K. Asher, D.W. Benjamin AlliedSignal Aerospace, L. Keith Bennett Alon Processing Inc, A. Blair, R.R. Brookshire Brushtronics Engineering, M.E. Browning, R.C. Buckley, J.R. Davis Davis, C.A. Deckert Shipley Company, J.S. Feeley, H.D. Ferrier, J. Quaker, Volume Chairpersons The Volume Chairpersons were Authors and Contributors, n.d.
  • [17] D. Vojtěch, P. Novák, P. Macháč, M. Morťaniková, K. Jurek, Surface protection of titanium by Ti5Si3 silicide layer prepared by combination of vapour phase siliconizing and heat treatment, J. Alloys Compd. 464 (2008) 179–184. https://doi.org/10.1016/j.jallcom.2007.10.020.
  • [18] C. Nobili, F. Nava, G. Ottaviani, M. Costato, G. DE Santi, G. Queirolo, TITANIUM SILICIDE FORMATION IN PRESENCE OF OXYGEN, 1992.

Year 2022, Volume: 3 Issue: 1, 11 - 21, 29.06.2022

Eşref Furkan Tepe Gözde Çelebi Efe Tuba Yener

Abstract

Supporting Institution

Sakarya Uygulamalı Bilimler Üniversitesi BAPK

Project Number

2021-50-01-063

References

  • [1] M. Jackson, R.R. Boyer, Titanium and its Alloys: Processing, Fabrication and Mechanical Performance, Encycl. Aerosp. Eng. (2010) 1–16. https://doi.org/10.1002/9780470686652.eae199.
  • [2] R. Boyer, G. Welsch, E.W. Collings, Materials properties handbook : titanium alloys, 1994.
  • [3] K. Chou, P.W. Chu, E.A. Marquis, Early oxidation behavior of Si-coated titanium, Corros. Sci. 140 (2018) 297–306. https://doi.org/10.1016/j.corsci.2018.05.035.
  • [4] M. Hetmańczyk, L. Swadźba, B. Mendala, Advanced materials and protective coatings in aero-engines application co-operating with Manufacturing and processing, 2007. www.journalamme.org.
  • [5] F.J. Pérez, M.P. Hierro, M.C. Carpintero, F.J. Bolivar, Aluminum and silicon co-deposition by the chemical vapor deposition in fluidized bed reactor technique as a precursor of protective coatings of mullite, Surf. Coatings Technol. 184 (2004) 361–369. https://doi.org/10.1016/j.surfcoat.2003.11.001.
  • [6] R. Bianco, R.A. Rapp, Pack cementation diffusion coatings, Metall. Ceram. Prot. Coatings. (1996) 236–260. https://doi.org/10.1007/978-94-009-1501-5_9.
  • [7] T.R. Rautray, R. Narayanan, T. Kwon, K. Kim, Surface Modification of Titanium and Titanium Alloys by Ion Implantation Review Surface Modification of Titanium and Titanium Alloys by Ion Implantation, (2010). https://doi.org/10.1002/jbm.b.31596.
  • [8] A.R. Castle, D.R. Gabe, Chromium diffusion coatings The application of diffusion coatings has become, 1999.
  • [9] W. Yang, J. Park, K. Choi, C.H. Chung, J. Lee, J. Zhu, F. Zhang, J.S. Park, Evaluation of growth kinetics of aluminide coating layers on Ti-6Al-4V alloys by pack cementation and the oxidation behaviours of the coated Ti-6Al-4V alloys, Int. J. Refract. Met. Hard Mater. 101 (2021) 105642. https://doi.org/10.1016/j.ijrmhm.2021.105642.
  • [10] D. Vojtěch, B. Bártová, T. Kubatík, High temperature oxidation of titanium-silicon alloys, Mater. Sci. Eng. A. 361 (2003) 50–57. https://doi.org/10.1016/S0921-5093(03)00564-1.
  • [11] G.Ç. Efe, İ. Altınsoy, T. Yener, M. İpek, C. Bindal, S. Zeytin, Surface Modifi cation of Ti6Al4V Alloy by Pack Siliconizing Method, (2018) 1024–1027.
  • [12] A.E. Kochmańska, A. Jarlaczyńska, J. Baranowska, Formation of silicide and silicide-aluminide coatings on molybdenum alloy during slurry cementation process: Influence of slurry volume, Materials (Basel). 14 (2021). https://doi.org/10.3390/ma14226940.
  • [13] T. Shimozaki, T. Okino, M. Yamane, Y. Wakamatsu, M. Onishi, Effect of impurities on growth of Ti silicides in bulk Ti/Si diffusion couple, Mater. Trans. JIM. 38 (1997) 865–870. ttps://doi.org/10.2320/matertrans1989.38.865.
  • [14] A. Paul, S. Divinski, Handbook of Solid State Diffusion, First edit, Elsevier Inc., 2017.
  • [15] B. Cockeram, G. Wang, The influence of multi-layered kinetics on the selection of the primary phase during the diffusion-controlled growth of titanium-silicide layers, 1995.
  • [16] C.M. Cotell, J.A. Sprague, F.A. Smidt, R. Menezes Nunes UFRGS, R.K. Asher, D.W. Benjamin AlliedSignal Aerospace, L. Keith Bennett Alon Processing Inc, A. Blair, R.R. Brookshire Brushtronics Engineering, M.E. Browning, R.C. Buckley, J.R. Davis Davis, C.A. Deckert Shipley Company, J.S. Feeley, H.D. Ferrier, J. Quaker, Volume Chairpersons The Volume Chairpersons were Authors and Contributors, n.d.
  • [17] D. Vojtěch, P. Novák, P. Macháč, M. Morťaniková, K. Jurek, Surface protection of titanium by Ti5Si3 silicide layer prepared by combination of vapour phase siliconizing and heat treatment, J. Alloys Compd. 464 (2008) 179–184. https://doi.org/10.1016/j.jallcom.2007.10.020.
  • [18] C. Nobili, F. Nava, G. Ottaviani, M. Costato, G. DE Santi, G. Queirolo, TITANIUM SILICIDE FORMATION IN PRESENCE OF OXYGEN, 1992.
There are 18 citations in total.

Details

Primary Language English
Subjects Artificial Intelligence
Journal Section Research Articles
Authors

Eşref Furkan Tepe

Gözde Çelebi Efe

Tuba Yener

Project Number 2021-50-01-063
Publication Date June 29, 2022
Published in Issue Year 2022 Volume: 3 Issue: 1

Cite

APA Tepe, E. F., Çelebi Efe, G., & Yener, T. (2022). EFFECT of TEMPERAUTRE on PACK SILICONIZING of Ti6Al4V ALLOY. Journal of Smart Systems Research, 3(1), 11-21.
AMA Tepe EF, Çelebi Efe G, Yener T. EFFECT of TEMPERAUTRE on PACK SILICONIZING of Ti6Al4V ALLOY. JoinSSR. June 2022;3(1):11-21.
Chicago Tepe, Eşref Furkan, Gözde Çelebi Efe, and Tuba Yener. “EFFECT of TEMPERAUTRE on PACK SILICONIZING of Ti6Al4V ALLOY”. Journal of Smart Systems Research 3, no. 1 (June 2022): 11-21.
EndNote Tepe EF, Çelebi Efe G, Yener T (June 1, 2022) EFFECT of TEMPERAUTRE on PACK SILICONIZING of Ti6Al4V ALLOY. Journal of Smart Systems Research 3 1 11–21.
IEEE E. F. Tepe, G. Çelebi Efe, and T. Yener, “EFFECT of TEMPERAUTRE on PACK SILICONIZING of Ti6Al4V ALLOY”, JoinSSR, vol. 3, no. 1, pp. 11–21, 2022.
ISNAD Tepe, Eşref Furkan et al. “EFFECT of TEMPERAUTRE on PACK SILICONIZING of Ti6Al4V ALLOY”. Journal of Smart Systems Research 3/1 (June 2022), 11-21.
JAMA Tepe EF, Çelebi Efe G, Yener T. EFFECT of TEMPERAUTRE on PACK SILICONIZING of Ti6Al4V ALLOY. JoinSSR. 2022;3:11–21.
MLA Tepe, Eşref Furkan et al. “EFFECT of TEMPERAUTRE on PACK SILICONIZING of Ti6Al4V ALLOY”. Journal of Smart Systems Research, vol. 3, no. 1, 2022, pp. 11-21.
Vancouver Tepe EF, Çelebi Efe G, Yener T. EFFECT of TEMPERAUTRE on PACK SILICONIZING of Ti6Al4V ALLOY. JoinSSR. 2022;3(1):11-2.
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