Research Article
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Method Validation for The Determination of Toxic Elements in Fizzy Fruity Mineral Water Drinks Using ICP-MS

Year 2019, Volume: 2 Issue: 2, 38 - 41, 06.12.2019

Serpil Kılıç Murat Kılıç

Abstract

The presence of metallic impurities in fizzy fruity mineral water drinks
can constitute health hazards to the public. In this study, the Inductively
Coupled Plasma Mass Spectrometry (ICP-MS) was chosen to be validated, and
applied in suitable method of analysis for determination of antimony, lead and
cadmium in samples. The detection limits, quantification limits, linearity,
accuracy parameters were studied under optimised ICP-MS conditions. The method
trueness was confirmed by using certified references materials LGC soft drink
and obtained results were had acceptable Z-score values. The results obtained
make the method suitable for a precise determination of validated elements in
different brands of samples at these low concentration values.  Also, the results obtained were check with
permissible levels, daily intake (EDI), target hazard quotient (THQ) and hazard
index (HI).

Keywords

Fizzy fruity mineral water Health risk ICP-MS

Supporting Institution

AKDENİZ ÜNİVERSİTESİ

Project Number

FBA-2019- 4371

Thanks

This work was financially supported by the University of Akdeniz Scientific Research Projects Support Unit (FBA-2019- 4371).

References

  • Arif TJ, Mudsser A, Kehkashan S, Arif A, Inho C, Qazi M and Rizwanul H 2015. Heavy Metals and Human Health: Mechanistic Insight into Toxicity and Counter Defense System of Antioxidants. Int. J. Mol. Sci., 16: 29592-29630.
  • Astel A, Michalski R, Lyko A, Czapla MJ, Bigus K, Szopa S and Kwiecinska A 2014 Characterization of bottled mineral waters marketed in Poland using hierarchical cluster analysis. Journal of Geochemical Exploration, 143: 136-145.
  • Baba A, Ereeş FS, Hıçsönmez Ü, Çam S and Özdılek HG 2008. An assessment of the quality of various bottled mineral water marketed in Turkey. Environmental Monitoring Assessment, 139: 277–285.
  • Barbara BAF, Daniel MB and Ricardo JC 2015. Determination of metals in soft drinks packed in different materials by ETAAS. Food Chem, 185:488-494.
  • Bertoldi D, Bontempo L, Larcher R, Nicolini G, Voerkelius S, Lorenz GD, Ueckermann H, Froeschl H, Baxter MJ, Hoogewerff J and Brereton P 2011. Survey of the chemical composition of 571 European bottled mineral waters. Journal of Food Composition and Analysis, 24 (3): 376-385.
  • EC 1998. COUNCIL DIRECTIVE 98/83/EC of 3 November 1998 on the quality of water intended for human consumption. Official Journal of the European Communities 330: 32.
  • EU 2003. EU Directive 2003/40/EC, Establishing the list, concentration limits and labeling requirements for the constitu0065nts of natural mineral waters and the conditions for using ozone-enriched air for the treatment of natural mineral waters and spring waters. Official Journal of the European Communities 126, 34–39 (22.05.2003).
  • EU 2014. EUROPEAN UNION (Drinking water) Regulations, S.I. No. 122, 21, available from http://www.irishstatutebook.ie/eli/2014/si/122/made/en/pdfEURACHEM 1998. The Fitness for Purpose of Analytical Methods: A Laboratory Guide to Method Validation and Related Topics. EURACHEM: Uppsala, Sweden, 75 pp. https://www.eurachem.org/images/stories/Guides/pdf/valid.pdf
  • FAO/WHO 1997. FAO/WHO Food Consumption and Exposure Assessment of Chemicals. Report of FAO/WHO Consultation WHO, Geneva pp. 17–25.Galadima A and Garba ZN 2012. Heavy metals pollution in Nigeria: causes and consequences. Elixir Pollut., 45: 7917-7922.
  • Gutierrez-Reguera F, Montoya-Mayor R, Seijo-Delgado I and Ternero-Rodríguez M 2016. Chemical analysis and nutritional assessment of trace elements in natural mineral waters bottled in Spain. Afinidad, 73 (574): 102-118.
  • IARC 2006. Inorganic and organic lead compounds. IARC Monographs on the Evaluation of Carcinogenic Risks to Human 87: 519.
  • Kilic S, Yenisoy-Karakas S and Kilic M 2015 Metal contamination in fruit juices in Turkey: Method validation and uncertainty budget. Food Analytical Methods, 8: 2487–2495.
  • Kilic S, Cengiz MF and Kilic M 2018a. Monitoring of metallic contaminants in energy drinks using ICP-MS. Environmental Monitoring and Assessment, 190:202.
  • Kilic S, Cam İB, Tongur T and Kilic M 2018b. Health risk assessment of exposure to heavy metals and aflatoxins via dietaryi of dried red pepper from marketplaces in Antalya, Southern Turkey. Journal of Food Science, 83(10): 2675-2681.
  • Lee HS, Cho YH, Park SO, Kye SH, Kim BH, Hahm TS, Kim M, Lee JO and Kim Cİ 2006. Dietary exposure of the Korean population to arsenic, cadmium, lead and mercury. Journal of Food Composition and Analysis, 19: 31-37.
  • Mendil D, Demirci Z, Tuzen M and Soylak M 2010. Seasonal investigation of trace element contents in commercially valuable fish species from the Black sea, Turkey. Food and Chemical Toxicology, 48(3): 865–870.
  • Misunda A, Frengstad B, Sewersd U and Reimanna C 1999. Variation of 66 elements in European bottled mineral Waters. The Science of the Total Environment, 243(244): 21-41.
  • Tchounwou PB, Yedjou CG, Patlolla AK and Sutton DJ 2012. Heavy metals toxicity and the environment. EXS, 101:133–164. Ubong IU, Obunwo C and Faafa A 2016. Essential and non-essential metals in soft drinks consumed and sold in Port Harcourt, Nigeria. RA J. Appl. Res, 2(8): 550-557.
  • WHO 2006. Guidelines for drinking-water quality, First Addendum to third edition. Recommendations, vol. 1 (available on: http://www.who.int/water_sanitation_health/ dwq/gdwq0506.pdf).
  • WHO 2009. Chapter 6: Dietary exposure assessment of chemicals in food. Principles and Methods for the Risk Assessment of Chemicals in Food, Environmental Health Criteria.
  • WHO 2011. Guidelines for drinking-water quality. World Health Organization, Fourth edition, pp. 564.
  • WHO 2003. Antimony in drinking-water – background document for development WHO Guidelines for Drinking-water Quality, Geneva: WHO.
  • UNEP/FAO/WHO 1992. Assessment of dietary intake of chemical contaminants. WHO/HPP/FOS/92.6, UNEP/GEMS/92.F2, United Nations Environmental Program, Nairobi.
  • USEPA 1989. Risk Assessment Guidance for Superfund Volume I Human Health Evaluation Manual (Part A) Interim Final, vol 1. Office of Emergency and Remedial Response U.S. Environmental Protection Agency Washington, DC. 20450.
  • USEPA 2009. United States Environmental Protection Agency, Risk-based concentration table. Philadelphia: United States Environmental Protection Agency, Washington, DC.
  • USEPA 2013. Risk based concentration table. Retrieved from https://www.epa.gov.reg3hwmd/risk/human/index.htm

Year 2019, Volume: 2 Issue: 2, 38 - 41, 06.12.2019

Serpil Kılıç Murat Kılıç

Abstract

Project Number

FBA-2019- 4371

References

  • Arif TJ, Mudsser A, Kehkashan S, Arif A, Inho C, Qazi M and Rizwanul H 2015. Heavy Metals and Human Health: Mechanistic Insight into Toxicity and Counter Defense System of Antioxidants. Int. J. Mol. Sci., 16: 29592-29630.
  • Astel A, Michalski R, Lyko A, Czapla MJ, Bigus K, Szopa S and Kwiecinska A 2014 Characterization of bottled mineral waters marketed in Poland using hierarchical cluster analysis. Journal of Geochemical Exploration, 143: 136-145.
  • Baba A, Ereeş FS, Hıçsönmez Ü, Çam S and Özdılek HG 2008. An assessment of the quality of various bottled mineral water marketed in Turkey. Environmental Monitoring Assessment, 139: 277–285.
  • Barbara BAF, Daniel MB and Ricardo JC 2015. Determination of metals in soft drinks packed in different materials by ETAAS. Food Chem, 185:488-494.
  • Bertoldi D, Bontempo L, Larcher R, Nicolini G, Voerkelius S, Lorenz GD, Ueckermann H, Froeschl H, Baxter MJ, Hoogewerff J and Brereton P 2011. Survey of the chemical composition of 571 European bottled mineral waters. Journal of Food Composition and Analysis, 24 (3): 376-385.
  • EC 1998. COUNCIL DIRECTIVE 98/83/EC of 3 November 1998 on the quality of water intended for human consumption. Official Journal of the European Communities 330: 32.
  • EU 2003. EU Directive 2003/40/EC, Establishing the list, concentration limits and labeling requirements for the constitu0065nts of natural mineral waters and the conditions for using ozone-enriched air for the treatment of natural mineral waters and spring waters. Official Journal of the European Communities 126, 34–39 (22.05.2003).
  • EU 2014. EUROPEAN UNION (Drinking water) Regulations, S.I. No. 122, 21, available from http://www.irishstatutebook.ie/eli/2014/si/122/made/en/pdfEURACHEM 1998. The Fitness for Purpose of Analytical Methods: A Laboratory Guide to Method Validation and Related Topics. EURACHEM: Uppsala, Sweden, 75 pp. https://www.eurachem.org/images/stories/Guides/pdf/valid.pdf
  • FAO/WHO 1997. FAO/WHO Food Consumption and Exposure Assessment of Chemicals. Report of FAO/WHO Consultation WHO, Geneva pp. 17–25.Galadima A and Garba ZN 2012. Heavy metals pollution in Nigeria: causes and consequences. Elixir Pollut., 45: 7917-7922.
  • Gutierrez-Reguera F, Montoya-Mayor R, Seijo-Delgado I and Ternero-Rodríguez M 2016. Chemical analysis and nutritional assessment of trace elements in natural mineral waters bottled in Spain. Afinidad, 73 (574): 102-118.
  • IARC 2006. Inorganic and organic lead compounds. IARC Monographs on the Evaluation of Carcinogenic Risks to Human 87: 519.
  • Kilic S, Yenisoy-Karakas S and Kilic M 2015 Metal contamination in fruit juices in Turkey: Method validation and uncertainty budget. Food Analytical Methods, 8: 2487–2495.
  • Kilic S, Cengiz MF and Kilic M 2018a. Monitoring of metallic contaminants in energy drinks using ICP-MS. Environmental Monitoring and Assessment, 190:202.
  • Kilic S, Cam İB, Tongur T and Kilic M 2018b. Health risk assessment of exposure to heavy metals and aflatoxins via dietaryi of dried red pepper from marketplaces in Antalya, Southern Turkey. Journal of Food Science, 83(10): 2675-2681.
  • Lee HS, Cho YH, Park SO, Kye SH, Kim BH, Hahm TS, Kim M, Lee JO and Kim Cİ 2006. Dietary exposure of the Korean population to arsenic, cadmium, lead and mercury. Journal of Food Composition and Analysis, 19: 31-37.
  • Mendil D, Demirci Z, Tuzen M and Soylak M 2010. Seasonal investigation of trace element contents in commercially valuable fish species from the Black sea, Turkey. Food and Chemical Toxicology, 48(3): 865–870.
  • Misunda A, Frengstad B, Sewersd U and Reimanna C 1999. Variation of 66 elements in European bottled mineral Waters. The Science of the Total Environment, 243(244): 21-41.
  • Tchounwou PB, Yedjou CG, Patlolla AK and Sutton DJ 2012. Heavy metals toxicity and the environment. EXS, 101:133–164. Ubong IU, Obunwo C and Faafa A 2016. Essential and non-essential metals in soft drinks consumed and sold in Port Harcourt, Nigeria. RA J. Appl. Res, 2(8): 550-557.
  • WHO 2006. Guidelines for drinking-water quality, First Addendum to third edition. Recommendations, vol. 1 (available on: http://www.who.int/water_sanitation_health/ dwq/gdwq0506.pdf).
  • WHO 2009. Chapter 6: Dietary exposure assessment of chemicals in food. Principles and Methods for the Risk Assessment of Chemicals in Food, Environmental Health Criteria.
  • WHO 2011. Guidelines for drinking-water quality. World Health Organization, Fourth edition, pp. 564.
  • WHO 2003. Antimony in drinking-water – background document for development WHO Guidelines for Drinking-water Quality, Geneva: WHO.
  • UNEP/FAO/WHO 1992. Assessment of dietary intake of chemical contaminants. WHO/HPP/FOS/92.6, UNEP/GEMS/92.F2, United Nations Environmental Program, Nairobi.
  • USEPA 1989. Risk Assessment Guidance for Superfund Volume I Human Health Evaluation Manual (Part A) Interim Final, vol 1. Office of Emergency and Remedial Response U.S. Environmental Protection Agency Washington, DC. 20450.
  • USEPA 2009. United States Environmental Protection Agency, Risk-based concentration table. Philadelphia: United States Environmental Protection Agency, Washington, DC.
  • USEPA 2013. Risk based concentration table. Retrieved from https://www.epa.gov.reg3hwmd/risk/human/index.htm
There are 26 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Articles
Authors

Serpil Kılıç 0000-0002-4940-1839

Murat Kılıç 0000-0003-1174-0197

Project Number FBA-2019- 4371
Publication Date December 6, 2019
Acceptance Date August 26, 2019
Published in Issue Year 2019 Volume: 2 Issue: 2

Cite

APA Kılıç, S., & Kılıç, M. (2019). Method Validation for The Determination of Toxic Elements in Fizzy Fruity Mineral Water Drinks Using ICP-MS. Eurasian Journal of Biological and Chemical Sciences, 2(2), 38-41.
AMA Kılıç S, Kılıç M. Method Validation for The Determination of Toxic Elements in Fizzy Fruity Mineral Water Drinks Using ICP-MS. Eurasian J. Bio. Chem. Sci. December 2019;2(2):38-41.
Chicago Kılıç, Serpil, and Murat Kılıç. “Method Validation for The Determination of Toxic Elements in Fizzy Fruity Mineral Water Drinks Using ICP-MS”. Eurasian Journal of Biological and Chemical Sciences 2, no. 2 (December 2019): 38-41.
EndNote Kılıç S, Kılıç M (December 1, 2019) Method Validation for The Determination of Toxic Elements in Fizzy Fruity Mineral Water Drinks Using ICP-MS. Eurasian Journal of Biological and Chemical Sciences 2 2 38–41.
IEEE S. Kılıç and M. Kılıç, “Method Validation for The Determination of Toxic Elements in Fizzy Fruity Mineral Water Drinks Using ICP-MS”, Eurasian J. Bio. Chem. Sci., vol. 2, no. 2, pp. 38–41, 2019.
ISNAD Kılıç, Serpil - Kılıç, Murat. “Method Validation for The Determination of Toxic Elements in Fizzy Fruity Mineral Water Drinks Using ICP-MS”. Eurasian Journal of Biological and Chemical Sciences 2/2 (December 2019), 38-41.
JAMA Kılıç S, Kılıç M. Method Validation for The Determination of Toxic Elements in Fizzy Fruity Mineral Water Drinks Using ICP-MS. Eurasian J. Bio. Chem. Sci. 2019;2:38–41.
MLA Kılıç, Serpil and Murat Kılıç. “Method Validation for The Determination of Toxic Elements in Fizzy Fruity Mineral Water Drinks Using ICP-MS”. Eurasian Journal of Biological and Chemical Sciences, vol. 2, no. 2, 2019, pp. 38-41.
Vancouver Kılıç S, Kılıç M. Method Validation for The Determination of Toxic Elements in Fizzy Fruity Mineral Water Drinks Using ICP-MS. Eurasian J. Bio. Chem. Sci. 2019;2(2):38-41.
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